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ChemInform Abstract: PHOTOISOMERIZATION OF 4‐PYRIDONES TO 2‐PYRIDONES
Chemischer Informationsdienst, 1974AbstractBestrahlung (Hg‐Mitteldrucklampe) der 4‐Pyridone (I) liefert die isomeren 2‐Pyridone (II) als Hauptprodukte, während die 4‐Pyridone (III) unter gleichen Bedingungen unverändert bleiben.
NOBUYUKI ISHIBE, JUN MASUI
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Journal of the Chemical Society, Chemical Communications, 1985
Lithiation of 1-methyl-4-pyridone with n-butyl-lithium at -78 °C proceeds smoothly at the C-2 position and 2-substituted-4-pyridones (1c–j) are obtained by subsequent reaction with electorphiles; lithiation of 1-methyl-2-pyridone takes place predominantly at the N-methyl, the lithio-derivative reacting rapidly, even at -78 °C with starting pyridone to ...
Premji Patel, John A. Joule
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Lithiation of 1-methyl-4-pyridone with n-butyl-lithium at -78 °C proceeds smoothly at the C-2 position and 2-substituted-4-pyridones (1c–j) are obtained by subsequent reaction with electorphiles; lithiation of 1-methyl-2-pyridone takes place predominantly at the N-methyl, the lithio-derivative reacting rapidly, even at -78 °C with starting pyridone to ...
Premji Patel, John A. Joule
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Pyridones as Potential Antitumor Agents
Journal of Pharmaceutical Sciences, 1979Based on the finding that 3-acetoxy-2-pyridone had reproducible activity against murine P-388 lymphocytic leukemia, derivatives in this series were synthesized and evaluated to determine structural parameters important for activity. Of the 32 compounds tested, 10 were active.
D R, Hwang, J S, Driscoll
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Ambident Reactivities of Pyridone Anions
Journal of the American Chemical Society, 2010The kinetics of the reactions of the ambident 2- and 4-pyridone anions with benzhydrylium ions (diarylcarbenium ions) and structurally related Michael acceptors have been studied in DMSO, CH(3)CN, and water. No significant changes of the rate constants were found when the counterion was varied (Li(+), K(+), NBu(4)(+)) or the solvent was changed from ...
Martin, Breugst, Herbert, Mayr
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Tetrachlorobis(2-pyridone)-bis(μ2-2-pyridone)-dicopper
Acta Crystallographica Section C Crystal Structure Communications, 1993In this structure two Cu II centres 3.4448 (11) A apart are bridged asymmetrically by two 2-pyridone ligands and each is further coordinated by three terminal ligands (two chlorides and one 2-pyridone). Each molecule has an approximate, non-crystallographic centre of symmetry.
A. J. Blake, R. E. P. Winpenny
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Chemical Physics Letters, 2000
Abstract DFT/B3-LYP(6-31++G**) calculations are used to provide information on closed N – H ⋯ O H -bonded complexes, containing two hydrogen bonds. The studied model systems with two H-bonds are the 2-pyridone dimer, 2-pyridone–H2O and 2-pyridone–CH3OH.
A. Dkhissi +4 more
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Abstract DFT/B3-LYP(6-31++G**) calculations are used to provide information on closed N – H ⋯ O H -bonded complexes, containing two hydrogen bonds. The studied model systems with two H-bonds are the 2-pyridone dimer, 2-pyridone–H2O and 2-pyridone–CH3OH.
A. Dkhissi +4 more
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Chlorosulfonation of 2-pyridones
Chemistry of Heterocyclic Compounds, 1974Chlorosulfonlyl-substituted 2-pyridones were obtained for the first time. The ability of 2-pyridone-3-sulfonyl chlorides to undergo conversion to sulfonylides of the pyridine series by the action of bases is shown in the case of 5,6,7,8-tetrahydro-2-quinolone-3-sulfonyl chloride.
N. P. Shusherina +2 more
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Pyridone‐Doped Acenes with Improved Stability
Chemistry – A European Journal, 2023AbstractBesides the peripheral modification, the introduction of heteroatoms to modulate the property of longer acenes with improved chemical stability has been extensively studied for their potential applications in organic electronics. However, the utilization of 4‐pyridone, a common unit in the air‐ and photo‐stable acridone and quinacridone, to ...
Chengguo Yan, Weiwei Ding, Gang Zhang
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Electroorganic Oxidation of Pyridones
ECS Meeting Abstracts, 2018Electroorganic synthesis can be utilized as a green alternative in complex organic synthesis reactions for pharmaceutical compounds, mitigating or eliminating complex stoichiometric oxidants during organic synthesis. An electrochemical oxidation reaction can make a synthetic transformation more cost effective and more efficient when compared to ...
Dylan Daniel Rodene +4 more
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Photochemical Reactivity of Pyridones
ChemInform, 2003AbstractFor Abstract see ChemInform Abstract in Full Text.
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