Results 91 to 100 of about 23,799 (225)
Alkylidenecyclopropanes (ACPs) can work as versatile 3 C partners in a range of [3+n] cycloadditions with unsaturated carbon partners. We now demonstrate that they can also be harnessed for inter‐ and intramolecular palladium‐catalyzed [3+2] formal ...
Ricardo Rodiño +3 more
doaj +1 more source
This study demonstrates the use of atomic layer deposition to engineer an ultrathin MgxZnyOz oxide interphase on LiNiO2 cathodes, enhancing cycling stability and capacity retention in cobalt‐free lithium‐ion batteries. Lithium nickel oxide (LNO) is a promising cathode material for next‐generation high‐energy‐density lithium‐ion batteries owing to its ...
Orly Aminov +6 more
wiley +1 more source
A new family of pentamethylcyclopentadienyl (C5Me5, Cp*) iridium(III), rhodium(III), and ruthenium(III) complexes bearing bidentate 1,2‐dioxime ligands was developed and their catalytic performances were evaluated in the hydrogen‐borrowing‐type H/D exchange of amines using D2O as both solvent and deuterium source. Iridium derivatives achieved excellent
Francesco Taglieri +8 more
wiley +1 more source
Electrochemical C─H Amination From a Primary Amine via a Cobalt Nitrene Intermediate
This article reveals proof of principle to unlock the use of unfunctionalized amines as nitrene precursor alternatives, extending the applicability of metal nitrene transfer catalysis. Electrochemical generation of a cobalt nitrene intermediate from 4‐phenylbutylamine leads to C─H amination, producing the cyclic imine 2‐phenylpyrroline.
Demi D. Snabilié +8 more
wiley +1 more source
Mechanochemistry as an Emerging Tool for Organofluorine Chemistry
Fluorinated scaffolds are central across many areas of chemistry, driving the demand for efficient and sustainable synthetic methods. Mechanochemistry has emerged as a powerful alternative to conventional approaches, offering reduced environmental impact, shorter reaction times, and unique reactivity and selectivity.
Marie Caldiero +3 more
wiley +1 more source
Counterion Effects on the Properties and Reactivity of Charged Photoredox Catalysts
The choice of a counterion for a charged photocatalyst has long been overlooked. In this review, we summarize recent reports on counterion effects in photocatalysis, providing readers with a comprehensive theoretical understanding and synthetic applications for the use of a carefully chosen counterion. Electrostatic interactions represent the strongest
Elina K. Taskinen, Burkhard König
wiley +1 more source
Eight metabolites for N‐pyrrolidino fluetonitazene were identified in vitro, three of which (M2, M6 and M8) were present in an authentic urine sample. M2 was the most abundant in vivo metabolite and is a common marker metabolite of nitazepyne‐type substances.
Severin Zemp +6 more
wiley +1 more source
Overview of MSG‐assisted GABA enrichment and associated changes in amino acid, fatty acid, and volatile metabolite profiles in germinated black highland barley. ABSTRACT γ‐Aminobutyric acid (GABA) is a functional amino acid with multiple health benefits; however, the mechanism of its enrichment in black highland barley, particularly through precursor ...
Xiaohang Lu, Nana Ma, Yuan Wang
wiley +1 more source
Mycobacterium tuberculosis–host interactions and infection outcomes. Following initial infection, alveolar macrophages phagocytose the pathogen, prompting the recruitment of innate immune cells including neutrophils, NK cells, and interstitial macrophages.
Xiaojuan Zhang +3 more
wiley +1 more source
Schematic representation of the experimental design and the proposed mechanisms underlying the cardioprotective and anti‐atherosclerotic effects of Greek‐derived berry extracts. C57BL/6 mice with WD–induced MS and ApoE−/− mice with atherosclerosis received chronic supplementation with WMex or BBex.
Lydia Symeonidi +15 more
wiley +1 more source

