Antioxidants Inhibit Indoleamine 2,3-Dioxygenase in IFN-γ-Activated Human Macrophages: Posttranslational Regulation by Pyrrolidine Dithiocarbamate [PDF]
Shane R. Thomas+5 more
openalex +1 more source
Diastereodivergent Asymmetric 1,3-Dipolar Cycloaddition of Azomethine Ylides and β-Fluoroalkyl Vinylsulfones: Low Copper(II) Catalyst Loading and Theoretical Studies [PDF]
Cheng, Feng+7 more
core +1 more source
Synthesis of Rhamnose‐Modified Lewis‐X‐Containing Saponins
We report the synthesis of betulinic acid and echinocystic acid saponins featuring an unnatural analogue of the Lewis‐X trisaccharide, in which the l‐fucose residue is replaced by l‐rhamnose. These triterpenoid saponins were designed as negative controls for dendritic cell‐specific intercellular adhesion molecule‐3‐grabbing non‐integrin (DC‐SIGN ...
Oscar Javier Gamboa Marin+3 more
wiley +1 more source
Substituted Spiro[pyrrolidine-5,2'-tricyclo[3.3.1.13,7]decane] Derivatives
Vassil St. Georgiev+5 more
openalex +1 more source
Green‐light Cerium Photocatalysis enabled by Pyridine N‐oxide Ligands
Abstract: We report pyridine N‐oxides as neutral ligands in cerium photocatalysis. By using those neutral ligands, photoactive Ce(IV)‐species are generated, that show an extensive bathochromic shift compared to previously employed cerium‐based complexes. This allows the effective utilization of green light in the redox‐neutral CH‐hydrazination of small
Nicolas Müller+3 more
wiley +1 more source
Stereoselective Chemoenzymatic Cascades for the Synthesis of Densely Functionalized Iminosugars. [PDF]
Swanson CRB+4 more
europepmc +1 more source
Efficient stereoselective syntheses of piperidine, pyrrolidine, and indolizidine alkaloids [PDF]
Dieter Enders, Christoph Thiebes
openalex +1 more source
Electrochemical Hydrogenation of N‐Heterocycles and Related Substrates: A Mini‐Review
ABSTRACT Catalytic hydrogenation refers to the (often) metal‐mediated addition of dihydrogen (H2) equivalents to unsaturated compounds to form new element‐hydrogen bonds. This conceptually simple reaction is ubiquitous in the production of a vast number of essential chemicals.
Esteban Garcia‐Torres+1 more
wiley +1 more source
B(C6F5)3-Catalyzed Dehydrogenation of Pyrrolidines to Form Pyrroles. [PDF]
Alvarez-Montoya A+8 more
europepmc +1 more source