Selective Transfer Hydrogenation of Furfural to Isopropyl Levulinate: An In Situ One‐Pot Cascade Approach [PDF]
In this article, we applied a combination of metal (0.5 mol%) and acid (1 mol%) that functioned harmoniously to selectively convert a bio‐based starting material, furfural, into small oxygenates. We used a transfer hydrogenation reaction with isopropanol acting as both the reducing agent and the reaction medium. Isopropyl levulinate, a key intermediate
Subramaniyan S +2 more
europepmc +2 more sources
Synthesis and Biological Evaluation of Thieno[3,2-d]- pyrimidinones, Thieno[3,2-d]pyrimidines and Quinazolinones: Conformationally Restricted 17b-Hydroxysteroid Dehydrogenase Type 2 (17b-HSD2) Inhibitors [PDF]
In this study, a series of conformationally restricted thieno[3,2-d]pyrimidinones, thieno[3,2-d]pyrimidines and quinazolinones was designed and synthesized with the goal of improving the biological activity as 17-hydroxysteroid dehydrogenase type 2 ...
Hartmann, Rolf W. +2 more
core +1 more source
Synthesis of the Pyrrolidinone Core of KSM-2690 B
[reaction: see text] The first synthesis of the pyrrolidinone core of the polyene beta-lactone antibiotic KSM-2690 B is described. An ammonia-free Birch reductive aldol reaction utilizing acetaldehyde is one of the key steps, together with a ruthenium-catalyzed alkene isomerization reaction.
Donohoe, T, Chiu, J, Thomas, R
openaire +2 more sources
Templated Native Silk Smectic Gels [PDF]
One aspect of the present invention relates to a method of preparing a fibrous protein smectic hydrogel by way of a solvent templating process, comprising the steps of pouring an aqueous fibrous protein solution into a container comprising a solvent that
Jin, Hyoung-Joon +2 more
core +4 more sources
I. INCORPORATION OF FUNCTIONALITY AT THE β-POSITION FOR THE ZINC-MEDIATED CHAIN EXTENSION REACTION II. FORMAL SYNTHESIS OF HELIOTRIDANE AND PSEUDOHELIOTRIDANE THROUGH A ZINC-MEDIATED CHAIN EXTENSION APPROACH [PDF]
The zinc-mediated chain extension reaction has been previously developed to incorporate alkyl or aryl substituents at the β position of the chain-extended product.
Arnista, Nicholas Alexander
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Synthesis and Characterization of Polymeric Materials Derived From Multifunctional Alkyl a-Hydroxymethylacrylates [PDF]
The research presented in this dissertation covers the investigation of new materials derived from alkyl a-hydroxymethylacrylates (RHMA). The first project exposed in Chapter II involves the synthesis, characterization of RHMA-based reactive surfactants ...
Morizur, Jean-Francois
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Synthesis of Functionalized Pyrrolidinone Scaffolds via Smiles-Truce Cascade. [PDF]
Sephton T +3 more
europepmc +1 more source
Ionisation and Dissociation of Diarylmethyl Chlorides in BCl3/CH2Cl2 Solution [PDF]
Mayr, Herbert +2 more
core +1 more source
Pyrrolidinones as Modulators of Neurogenesis [PDF]
openaire +2 more sources
Synthesis and structural investigation of some 1,4-disubstituted-2-pyrrolidinones
Kristina Brokaite +2 more
doaj +1 more source

