Asymmetric Organocatalytic Reductive Coupling Reactions between Benzylidene Pyruvates and Aldehydes.
Organic Letters, 2016 An organocatalytic three-component reductive coupling reaction between dimethyl phosphite, benzylidene pyruvates, and aldehydes is reported. A chiral triaryliminophosphorane catalyst promotes Pudovik addition, which is followed by phospha-Brook ...
M. Horwitz +3 more
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Lactate oxidation at the mitochondria: a lactate-malate-aspartate shuttle at work
Frontiers in Neuroscience, 2014 Lactate, the conjugate base of lactic acid occurring in aqueous biological fluids, has been derided as a dead-end waste product of anaerobic metabolism.
Daniel A Kane
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Chiral transition-metal complexes as Brønsted-acid catalysts for the asymmetric Friedel-Crafts hydroxyalkylation of indoles. [PDF]
, 2014 15.09.14 KB.
Carmona, D +8 more
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Synthesis, characterization and thermal behaviour on solid pyruvates of light trivalent lanthanides
Eclética Química, 2018 Solid State Ln-L compounds, where Ln stands for light trivalent lanthanides (La – Gd) and L is pyruvate, have been synthesized. Thermogravimetry and derivative thermo- gravimetry (TG/DTG), differential scanning calorimetry (DSC), X-Ray powder ...
A. B. Siqueira +5 more
doaj +1 more source
Synthesis, characterization and thermal behaviour on solid pyruvates of some bivalent metal ions.
Eclética Química, 2018 Solid state M-L compounds, were M stands for bivalent Mn, Fe, Co, Ni, Cu, Zn and L is pyruvate, have been synthesized. Thermogravimetry and derivative thermogravimetry (TG/DTG), differential scanning calorimetry (DSC), X-Ray powder diffractometry ...
Adriano Buzutti de Siqueira +3 more
doaj +1 more source
Hierarchical Harmonization of Atom-Resolved Metabolic Reactions across Metabolic Databases [PDF]
, 2021 Metabolic models have been proven to be useful tools in system biology and have been successfully applied to various research fields in a wide range of organisms.
Jin, Huan, Moseley, Hunter N. B.
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ANTICANCER POTENTIAL OF NOVEL PALLADIUM(II) COMPLEXES WITH ACYL PYRUVATES AS LIGANDS: DNA AND BSA INTERACTIONS AND MOLECULAR DOCKING STUDY [PDF]
STED JournalBearing in mind that some palladium complexes showed good antitumor potential while exhibiting less kidney toxicity comparing to cisplatin, to discover a new agents for chemotherapy with improved properties two novel palladium(II) complexes [Pd (L)2] (3A
Nenad Joksimović +4 more
doaj +1 more source
Prebiotic synthesis of phosphoenol pyruvate by α-phosphorylation-controlled triose glycolysis [PDF]
, 2017 Phosphoenol pyruvate is the highest-energy phosphate found in living organisms and is one of the most versatile molecules in metabolism. Consequently, it is an essential intermediate in a wide variety of biochemical pathways, including carbon fixation ...
A Eschenmoser +64 more
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Development of Catalytic Asymmetric Reactions of Pyruvates as Nucleophiles [PDF]
Okinawa Institute of Science and Technology Graduate UniversityDoctor of PhilosophyPyruvates or α-ketoesters, are important molecules in both organic chemistry and biology due to their intrinsic reactivity. Pyruvates can act as nucleophiles (reactions as
Mondal, Santanu
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Quantitative constraint-based computational model of tumor-to-stroma coupling via lactate shuttle [PDF]
, 2015 Cancer cells utilize large amounts of ATP to sustain growth, relying primarily on non-oxidative, fermentative pathways for its production.
CAPUANI, FABRIZIO +3 more
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