Synthesis of 13 C and 2 H Labeled Vinyl Pyruvate and Hyperpolarization of Pyruvate [PDF]
The hyperpolarization of nuclear spins has enabled unique applications in chemistry, biophysics, and particularly metabolic imaging. Parahydrogen-induced polarization (PHIP) offers a fast and cost-efficient way of hyperpolarization.
Arne Brahms +6 more
openalex +4 more sources
Quantitative constraint-based computational model of tumor-to-stroma coupling via lactate shuttle [PDF]
Cancer cells utilize large amounts of ATP to sustain growth, relying primarily on non-oxidative, fermentative pathways for its production.
CAPUANI, FABRIZIO +3 more
core +3 more sources
Adenosine Triphosphate and Carbon Efficient Route to Second Generation Biofuel Isopentanol. [PDF]
Climate change necessitates the development of CO2 neutral or negative routes to chemicals currently produced from fossil carbon. In this paper we demonstrate a pathway from the renewable resource glucose to next generation biofuel isopentanol by pairing
Chiniquy, Jennifer +9 more
core +1 more source
Kohn-Sham formalizmustól eltérő (hatványsoros) sűrűség funkcionál algoritmus kidolgozása kémiai potenciálfelületek vizsgálatára. = Non Kohn-Sham formalism density functional algorithm (using power series) for calculating chemical potential energy surfaces. [PDF]
A sűrűség funkcionálok (DFT) részletes analízisét végeztem. Ebben a több-elektron sűrűség tulajdonságait és viselkedését analizáltam a két Hohenberg-Kohn (HK) tétel tekintetében.
Kristyán, Sándor
core +1 more source
Prebiotic synthesis of phosphoenol pyruvate by α-phosphorylation-controlled triose glycolysis [PDF]
Phosphoenol pyruvate is the highest-energy phosphate found in living organisms and is one of the most versatile molecules in metabolism. Consequently, it is an essential intermediate in a wide variety of biochemical pathways, including carbon fixation ...
A Eschenmoser +64 more
core +1 more source
Synthesis, characterization and thermal behaviour on solid pyruvates of light trivalent lanthanides
Solid State Ln-L compounds, where Ln stands for light trivalent lanthanides (La – Gd) and L is pyruvate, have been synthesized. Thermogravimetry and derivative thermo- gravimetry (TG/DTG), differential scanning calorimetry (DSC), X-Ray powder ...
A. B. Siqueira +5 more
doaj +1 more source
Copper-catalyzed asymmetric methylation of fluoroalkylated pyruvates with dimethylzinc
The catalytic asymmetric methylation of fluoroalkylated pyruvates is shown with dimethylzinc as a methylating reagent in the presence of a copper catalyst bearing a chiral phosphine ligand. This is the first catalytic asymmetric methylation to synthesize
Kohsuke Aikawa +3 more
doaj +1 more source
Synthesis, characterization and thermal behaviour on solid pyruvates of some bivalent metal ions.
Solid state M-L compounds, were M stands for bivalent Mn, Fe, Co, Ni, Cu, Zn and L is pyruvate, have been synthesized. Thermogravimetry and derivative thermogravimetry (TG/DTG), differential scanning calorimetry (DSC), X-Ray powder diffractometry ...
Adriano Buzutti de Siqueira +3 more
doaj +1 more source
ANTICANCER POTENTIAL OF NOVEL PALLADIUM(II) COMPLEXES WITH ACYL PYRUVATES AS LIGANDS: DNA AND BSA INTERACTIONS AND MOLECULAR DOCKING STUDY [PDF]
Bearing in mind that some palladium complexes showed good antitumor potential while exhibiting less kidney toxicity comparing to cisplatin, to discover a new agents for chemotherapy with improved properties two novel palladium(II) complexes [Pd (L)2] (3A
Nenad Joksimović +4 more
doaj +1 more source
The relationships between transketolase, yeast pyruvate decarboxylase and pyruvate dehydrogenase of the pyruvate dehydrogenase complex [PDF]
The amino acid sequences of four thiamine pyrophosphate‐requiring enzymes were aligned with the published amino acid sequence of the transketolase of Hansenula polymorpha. Sequences of the combined α and β subunits of the E1 enzyme of the pyruvate dehydrogenase complexes of Homo sapiens and Bacillus stearothermophilus aligned well with the ...
Robinson, Brian H., Chun, Kathy
openaire +2 more sources

