Results 81 to 90 of about 5,059,105 (302)

HPLC Determination of α-keto Acids from Human Serum Using 2,3-Diamino-2,3-dimethylbutane as Derivatizing Reagent [PDF]

open access: yesPakistan Journal of Analytical & Environmental Chemistry, 2013
Seven α-keto acids, pyruvic acid (PYR), 2-oxobutyric acid (KB), 3-methyl-2-oxobutyric acid (MKBA), 3-methyl-2-oxovaleric acid (K3MVA), 4-methyl-2-oxovaleric acid (K4MVA), 2-oxoglutaric acid (KG) and Phenyl pyruvic acid (PPY) as derivatives of 2,3-diamino-
Khalida Parveen Mahar   +5 more
doaj  

The conversion of citrulline to arginine in kidney [PDF]

open access: yes, 1941
Glycocyamine is formed in the kidney by the transfer of the amidine group of arginine to the nitrogen atom of glycine. In the study of this reaction it was observed that glycocyamine was also formed from citrulline and glycine.
Borsook, Henry, Dubnoff, Jacob W.
core  

2‐oxoglutarate analogue‐based biomolecular tools for exploring structure‐activity relationships in non‐heme iron enzymes

open access: yesChemBioChem, Accepted Article.
2‐oxoglutarate (2OG)‐dependent non‐heme iron (NHFe) enzymes constitute a family of enzymes that use 2OG and oxygen to catalyze the hydroxylation of unactivated C(sp3)–H bonds. These enzymes are of biological importance and therapeutic interest due to their role in regulating various cellular processes. Herein, we have rationally designed two classes of
Peter Windsor   +3 more
wiley   +1 more source

Pyruvic Acid Production from Sucrose by Escherichia coli Pyruvate Dehydrogenase Variants

open access: yesFermentation, 2023
Sucrose is an abundant, cheap, and renewable carbohydrate which makes it an attractive feedstock for the biotechnological production of chemicals. Escherichia coli W, one of the few safe E.
W. Chris Moxley, Mark A. Eiteman
doaj   +1 more source

Mechanistic Description of Photochemical Oligomer Formation from Aqueous Pyruvic Acid.

open access: yesJournal of Physical Chemistry A, 2017
The aqueous phase photochemistry of pyruvic acid, an important oxidation product of isoprene, is known to generate larger oligomeric species that may contribute to the formation of secondary organic aerosol in the atmosphere.
Rebecca J. Rapf   +3 more
semanticscholar   +1 more source

A Bis‐Thiosemicarbazone Pd(II) SiO2 Nanoparticle Conjugate for CC Coupling Catalysis

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
The thiosemicarbazone (TSC) Pd complex–SiO2 nanoparticle conjugate [PdL]–APTES–SiO2 (APTES = (3‐aminopropyl)triethoxysilane) was synthesized through covalent binding of the pentadentate bis(N4‐(2‐ethylphenyl)) 2,6‐diacetyl‐pyridine TSC onto monodispersed SiO2, followed by coordination of Pd(II) and used as precatalysts in Suzuki–Miyaura‐type cross ...
Eric Tobechukwu Anthony   +5 more
wiley   +1 more source

Pyruvate-Associated Acid Resistance in Bacteria [PDF]

open access: yesApplied and Environmental Microbiology, 2014
ABSTRACT Glucose confers acid resistance on exponentially growing bacteria by repressing formation of the cyclic AMP (cAMP)-cAMP receptor protein (CRP) complex and consequently activating acid resistance genes. Therefore, in a glucose-rich growth environment, bacteria are capable of resisting acidic stresses due to low levels of cAMP-CRP ...
Yannan Li   +4 more
openaire   +3 more sources

Toward the Synthesis of 3,3‐Difluoro Deaminated Sialic Acid (C3DFKDN)

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
The synthesis of protected C3‐difluoro KDN (C3DFKDN), an unnatural derivative of the sialic acid member, KDN, and key building block for KDN‐based chemical probes, is reported. Its 12‐step synthetic route starts from commercially available methyl d‐mannopyranoside and key steps include a Reformatsky reaction with ethyl bromodifluoroacetate, alkylation ...
Lemeng Chao, Tom Wennekes
wiley   +1 more source

Effect of curd freezing and packaging methods on the organic acid contents of goat cheeses during storage

open access: yesMljekarstvo, 2011
Effects of freezing and packaging methods on organic acid content of goat cheese during 12 weeks of storage were determined. Goat cheese milk curds were divided into two batches; one of the batches was directly processed in to goat cheese while the other
Pınar Balkir   +3 more
doaj  

Rapid biodegradation of polycyclic aromatic hydrocarbons (PAHs) using effective Cronobacter sakazakii MM045 (KT933253)

open access: yesMethodsX, 2017
Polycyclic Aromatic Hydrocarbons (PAHs) are complex and widely distributed environmental pollutants that can affect living ecosystems. This study was conducted to rapidly degrade phenanthrene and pyrene representing low and high molecular weight of PAHs,
Zubairu Darma Umar   +3 more
doaj   +1 more source

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