Results 21 to 30 of about 276 (121)
Redox‐Dependent Luminescence in a Pentavalent Uranyl Complex
Redox‐dependent luminescence in a molecular pentavalent uranyl complex supported by a pyridine dipyrrolide pincer ligand is presented. Electrochemical and chemical reduction of the uranyl(VI) species provides a stable uranyl(V) complex that emits blue light from a high‐energy excited state. The anti‐Kasha emission is credited to the presence of “nested”
Leyla R. Valerio +5 more
wiley +1 more source
Co-ordination behaviour of a novel tristhiourea tripodal ligand; structural variations in a series of transition metal complexes [PDF]
The co-ordination chemistry of a tristhiourea tris(2-pyridylmethyl)amine ligand (L1) with a series of transition metal ions has been investigated. Crystallographic data show that large metal ions, with no geometrical preferences , such as Mn(II) and Cd ...
Amoroso, Angelo James +3 more
core +1 more source
Impurity‐tolerance exhibited by Re molecular complex for CO2 conversion from flue gas containing 10% CO2, 10% O2, 100 ppm NO2 and 50 ppm SO2 in N2 matrix. This tolerance is based on electrochemical reduction of gas impurities on the electrode surface under CO2 electrolysis conditions.
Yutzil Segura‐Ramirez +4 more
wiley +1 more source
Application of mixed formulations of quasi-reversibility to solve ill-posed problems for heat and wave equations: the 1d case [PDF]
International audienceIn this paper we address some ill-posed problems involving the heat or the wave equation in one dimension, in particular the backward heat equation and the heat/wave equation with lateral Cauchy data.
A. Ern +29 more
core +5 more sources
Restoring quasireversibility with a single topological charge [PDF]
We numerically study a rotating Bose-Einstein condensate placed transiently over the critical rotation frequency i.e. in a regime where the rotation frequency is larger than the radial frequency of the confinement. We study the reversibility of this process depending on the strength of the interactions and the presence of vortices.
Álvarez Zúñiga, Juan Pablo +4 more
openaire +4 more sources
Sulfur‐Rich μ‐O Diiron Catalyst for Electrochemical Hydrogen Production
A diferric μ‐oxido complex supported by a sulfur‐rich scaffold acts as a proton‐reduction electrocatalyst for H2 production via a μ‐hydroxido species. An aminodithiophenolate scaffold with an NS2 donor set supports diiron complex formation. The diferrous precursor activates O2, giving rise to a diferric μ‐oxido species, which acts as a proton‐reduction
Hugo C. Hernández‐Toledo +7 more
wiley +1 more source
Eigenvalue control for a Finsler-Laplace operator [PDF]
Using the definition of a Finsler-Laplacian given by the first author, we show that two bi-Lipschitz Finsler metrics have a controlled spectrum. We deduce from that several generalizations of Riemannian results.
Barthelmé, Thomas, Colbois, Bruno
core
Completeness and incompleteness of the Binet-Legendre Metric
The goal of this short paper is to give condition for the completeness of the Binet-Legendre metric in Finsler geometry.
Matveev, Vladimir S., Troyanov, Marc
core +1 more source
Conductive silk‐polypyrrole scaffolds couple redox stability with cell‐affinitive peptides present innately in an endogenous silk fibroin, enabling optimized electrical stimulation to drive neurite outgrowth. Findings establish electrochemical‐biological link for biomaterial design rules for smart nerve guidance conduits that can provide low voltage ...
Rajiv Borah +5 more
wiley +1 more source
The influence of the potential pulse height of square-wave voltammetry (SWV) (i.e., the SW amplitude) is studied for a variety of quasireversible electrode mechanisms, including a simple solution-phase electrode reaction at a planar or spherical electrode, a solution phase electrode reaction coupled with a reversible follow-up chemical reaction, and a ...
Mirceski, V +3 more
openaire +2 more sources

