An iron‐photocatalyzed unsymmetrical 1,2‐hetero(atom)difunctionalization of alkenes enables to install orthogonal C–Cl and C–O (alkoxyamine) handles which provides access to diverse nucleophiles via complementary reactivity (SN and photoredox) at two distinct sites. Detailed mechanistic studies elucidate interesting features of the iron catalytic cycle.
Amrita Chaudhuri +5 more
wiley +2 more sources
Choline Chloride/Acetic Acid Deep Eutectic Solvent for the Doebner-von Miller Synthesis of 2-Arylquinolines and Their Reduction to 2-Aryl-1,2,3,4-tetrahydroquinolines. [PDF]
Paparella AN +4 more
europepmc +1 more source
Quinoline and Acridine Synthesis [PDF]
openaire +1 more source
Synthetic Strategies for the Construction of Cyclobutane‐Fused Heterocycles
Cyclobutane‐fused heterocycles are important motifs commonly present in bioactive compounds, recognized for their rigid 3D structures that confer unique properties. However, synthesizing these compounds remains challenging. This review discusses current methods for their synthesis, such as photochemical, metal‐catalyzed, and Lewis acid‐mediated [2 + 2]
Michela Vargiu +2 more
wiley +1 more source
A series of Ir(III) complexes (Ir‐1‐Ir‐4) based on imidazole derivatives provide a new afterglow luminescence mechanism. The work expands the range of afterglow luminescence frameworks to overcome: (i) a lack of new afterglow scaffolds; (ii) the dependence on initial external light activation; and (iii) aggregation‐caused quenching.
Zihan Wu +9 more
wiley +2 more sources
Overcoming the Dexter distance constraint: a relay strategy for asymmetric photocatalysis. [PDF]
Zeng H, Wu J.
europepmc +1 more source
Direct Assembly of a Fully Functionalized-Fragment Library for Photoaffinity Labeling Applications via Mild A<sup>3</sup>‑Coupling in Water. [PDF]
Bauhoff T +4 more
europepmc +1 more source
Skeletal editing by iron-catalyzed carbene insertion of trichloromethanes. [PDF]
DeMuynck BM +8 more
europepmc +1 more source
Visible-light promoted cascade annulation of <i>N</i>-propargylamines with sodium sulfinates to access sulfonylated 9<i>H</i>-pyrrolo[1,2-<i>a</i>]indoles and quinolines. [PDF]
Wu J, Dong H, Li Z.
europepmc +1 more source
Phosphine-mediated azine C-H couplings with water and ammonia. [PDF]
Nottingham KG +6 more
europepmc +1 more source

