The second‐generation crystalline sponge method allows structurally diverse molecular guests to crystallize under standardized crystallization conditions. The key is the predominant packing type of cages and anions in crystals. ABSTRACT Crystallization is typically highly sensitive to even minor structural differences in target molecules.
Wei He, Hiroki Takezawa, Makoto Fujita
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This minireview highlights recent advances in catalyst development and mechanistic strategies that enable photochemical and photocatalytic reactivity under 700–1000 nm NIR light, emphasizing how long‐wavelength excitation expands opportunities in both synthetic chemistry and biology.
Santosh K. Pagire +3 more
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Site-Selective C6-β-Aminoalkylation of Tetrahydroquinolines with N-Arylsulfonyl Aryl Aziridines in Hexafluoroisopropanol: A Modular Approach to C6-Alkylated Quinolines. [PDF]
Taskesenligil Y, Aslan M, Saracoglu N.
europepmc +1 more source
Planar Chirality Controls Diastereotopicity in [2.2]Paracyclophanyl Cyclopropenes
In this work, we report the synthesis of [2.2]paracyclophane‐substituted cyclopropenes via rhodium‐catalyzed cyclopropenation using a pCp‐derived carbene precursor. The planar chiral framework induces diastereotopic differentiation of otherwise equivalent alkyl substituents, which is reflected in their 1H NMR spectra.
Tilman Köhler +3 more
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Regio- and chemoselective catalytic partial transfer hydrogenation of quinolines by dinuclear aluminum species. [PDF]
Liu X +4 more
europepmc +1 more source
Selective Hydrogenation of Heteroarenes Using Supported Ruthenium Phosphide Nanoparticle Catalysts. [PDF]
Ghazi Zahedi H +9 more
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<i>In vitro</i> and <i>in vivo</i> studies of dehydroxylated-isoquines and -isotebuquines against trypanosomatids: a preclinical drug candidate for treatment of cutaneous leishmaniasis. [PDF]
Romero AH +9 more
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Photocatalytic Hydrogenation of Quinolines to Form 1,2,3,4-Tetrahdyroquinolines Using Water as the Hydrogen Atom Donor. [PDF]
Zhang J +6 more
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Organic azides are readily reduced to amines under mild conditions by ammonia borane complex, catalyzed by a low loading level of reusable Au nanoparticles supported on TiO2. We present the first protocol for the chemoselective reduction of organic azides to amines by ammonia borane complex. In the presence of a low catalytic amount of Au nanoparticles
Elisavet‐Maria Zantioti‐Chatzouda +5 more
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