Results 111 to 120 of about 64,113 (206)

Catalytic Generation of Cationic Gold Carbene Complexes From 7‐Alkynylnorbornadienes and Their Intermolecular Cyclopropanation With Alkenes

open access: yesChemistry – A European Journal, EarlyView.
Efficient cationic gold(I)‐catalyzed intermolecular cyclopropanation of 7‐alkynylnorbornadiene derivatives has been developed. This methodology offers the synthesis of a new class of norbornene derivatives in high yield with excellent diastereoselectivity.
Kento Ishida   +3 more
wiley   +1 more source

Coordinative‐Guest‐Triggered Dimensional Crossover in a Metal–Organic Framework With Rigid Metal–Oxo Rods

open access: yesChemistry – A European Journal, EarlyView.
We report a reversible structural phase transition in a metal–organic framework (MOF) triggered by the exchange of coordinative guest molecules. This MOF consists of rigid 1D Pb–O rods as building units, forming a 3D framework with 1D pores. Guest exchange induces pronounced changes in both the Pb–O rod structure and the dimensionality of the framework.
Keisuke Ishikawa, Kazuya Otsubo
wiley   +1 more source

Stable Synapse-Like Memory Switching in N-Heterocyclic Carbene Monolayers. [PDF]

open access: yesAngew Chem Int Ed Engl
Das A   +11 more
europepmc   +1 more source

One‐Shot Pd(II)‐Catalyzed Multiple C–H Activation Enables Modular Construction of Fluorenylidene Oxindole‐Based Multi(Polycyclic) Aromatic Enes

open access: yesChemistry – A European Journal, EarlyView.
A one‐shot Pd(II)‐catalyzed C─H activation strategy enables the rapid conversion of simple linear propiolamides into structurally diverse mono‐, di‐, and tri‐olefin‐bridged MPAEs. This cascade process orchestrates up to six sequential C–H activations in a single operation, providing streamlined access to highly conjugated architectures.
Haiyu Wang   +4 more
wiley   +1 more source

A Potent Quinone Reductase Encoded by <i>ywqN</i> (Qnr1) Protects <i>Bacillus subtilis</i> from Oxygen Radical Genotoxicity. [PDF]

open access: yesMolecules
González BR   +6 more
europepmc   +1 more source

Cross‐Dehydrogenative Coupling Reactions With Redox‐Active Guanidine Reagents

open access: yesChemistry – A European Journal, EarlyView.
ABSTRACT Cross‐dehydrogenative coupling (CDC) reactions are attractive and environmentally friendly ways to form new C‐C and other element‐element bonds. Here, we report the first CDC reactions triggered by a redox‐active guanidine reagent. N‐phenyltetrahydroisoquinoline and derivatives with electron‐donating and withdrawing substituents at the N ...
Petra Walter   +2 more
wiley   +1 more source

Control of Gemcitabine Activity With Blue and Red Light

open access: yesChemistry – A European Journal, EarlyView.
Treating cancer with chemotherapy is generally associated with many side effects, which can be addressed by selectively releasing the desired drugs with visible light. Sixteen new blue light‐activatable cytostatics were introduced, with the gemcitabine derivative exhibiting ideal properties.
Nils F. Kersten   +6 more
wiley   +1 more source

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