Efficient cationic gold(I)‐catalyzed intermolecular cyclopropanation of 7‐alkynylnorbornadiene derivatives has been developed. This methodology offers the synthesis of a new class of norbornene derivatives in high yield with excellent diastereoselectivity.
Kento Ishida +3 more
wiley +1 more source
An early diverging SQR enzyme in Antarctic <i>Gloeobacterales</i> indicates sulfide tolerance in thylakoid-lacking cyanobacteria. [PDF]
Hambücken L +5 more
europepmc +1 more source
We report a reversible structural phase transition in a metal–organic framework (MOF) triggered by the exchange of coordinative guest molecules. This MOF consists of rigid 1D Pb–O rods as building units, forming a 3D framework with 1D pores. Guest exchange induces pronounced changes in both the Pb–O rod structure and the dimensionality of the framework.
Keisuke Ishikawa, Kazuya Otsubo
wiley +1 more source
Stable Synapse-Like Memory Switching in N-Heterocyclic Carbene Monolayers. [PDF]
Das A +11 more
europepmc +1 more source
A one‐shot Pd(II)‐catalyzed C─H activation strategy enables the rapid conversion of simple linear propiolamides into structurally diverse mono‐, di‐, and tri‐olefin‐bridged MPAEs. This cascade process orchestrates up to six sequential C–H activations in a single operation, providing streamlined access to highly conjugated architectures.
Haiyu Wang +4 more
wiley +1 more source
A Potent Quinone Reductase Encoded by <i>ywqN</i> (Qnr1) Protects <i>Bacillus subtilis</i> from Oxygen Radical Genotoxicity. [PDF]
González BR +6 more
europepmc +1 more source
Cross‐Dehydrogenative Coupling Reactions With Redox‐Active Guanidine Reagents
ABSTRACT Cross‐dehydrogenative coupling (CDC) reactions are attractive and environmentally friendly ways to form new C‐C and other element‐element bonds. Here, we report the first CDC reactions triggered by a redox‐active guanidine reagent. N‐phenyltetrahydroisoquinoline and derivatives with electron‐donating and withdrawing substituents at the N ...
Petra Walter +2 more
wiley +1 more source
A P-type pentatricopeptide repeat-containing protein interacts with the Japanese soil-borne wheat mosaic virus movement protein and modulates susceptibility to infection. [PDF]
Strauch CJ +8 more
europepmc +1 more source
Control of Gemcitabine Activity With Blue and Red Light
Treating cancer with chemotherapy is generally associated with many side effects, which can be addressed by selectively releasing the desired drugs with visible light. Sixteen new blue light‐activatable cytostatics were introduced, with the gemcitabine derivative exhibiting ideal properties.
Nils F. Kersten +6 more
wiley +1 more source
Advances in the Chemical Properties and Functional Applications of Urushiol: From Traditional Lacquerware to Modern Materials. [PDF]
Xu S, Liu Y, Chen W, Zhang J, Liu X.
europepmc +1 more source

