π‐Extended Salphen Scaffolds Enable CO2 Electroreduction and Singlet Oxygen Generation
New family of π‐extended salen ligands bearing phenylene bridge and tunable phenyl‐based substituents, and their corresponding boron difluoride complexes. Thanks to the extended π‐delocalization over the molecule, the ligands themselves show promising results in electrochemical CO2 reduction to CO, while the complexes act as efficient photosensitizers ...
Vincenzo Langellotti +10 more
wiley +1 more source
Tuning the Absorption Spectrum of Polydopamine via Post-Synthetic Oxidation with Bobbit's Salt. [PDF]
Chang C +7 more
europepmc +1 more source
Reactions of 10‐mesityl‐1,8‐diphenylanthracene with DDQ/TfOH produced three products via sequential formation of a five‐ or seven‐membered ring. Unexpectedly, the triply cyclized product with a rubicene substructure was formed through cyclization involving 1,2‐methyl shift.
Tatsuhiro Sasaki +2 more
wiley +1 more source
Controlling distance, time and reactivity: Chemical principles of proximity labeling. [PDF]
Ruenkam T, Wang Z, Juvekar V, Loh KH.
europepmc +1 more source
Well‐Defined Nickel Precatalysts: Form, Function, and Application
This review provides guidance on which nickel precatalysts to choose for a given application or which properties to prioritize in reaction development. A summary of the ease of synthesis, stability, diversity, accessibility, modularity, and general applicability is provided along with a related infographic.
Morgan E. John +3 more
wiley +1 more source
Oxidative Potential of Atmospheric Particulate Matter: A Review of the Role of Metal-Organic Interactions, Mechanistic Insights, and Key Determinants. [PDF]
Lin M, Yu JZ.
europepmc +1 more source
Self‐Immolative Poly(Benzyl Ether)s: Design Principles and Controlled Depolymerization
Unzipping to Sustainability: This Concept article explores the thermodynamic design of quinone‐methide (QM)‐based poly(benzyl ether)s (PBEs). It explains how a low ceiling temperature (Tc), QM stability, and an entropic gain drive rapid depolymerization (“unzipping”) of PBEs into monomers.
Ji Woo Kim, Yewon Kang, Hyungwoo Kim
wiley +1 more source
Development of Quantum dot-based enzyme biosensor for the detection of dopamine in urine. [PDF]
Yogaraju DS +4 more
europepmc +1 more source
Sustainable hydrogen production can be obtained from hydogen‐rich biomass‐derived organic molecules through Acceptorless Dehydrogenation (AD) reactions. Glycerol and sugars are available in large quantities from industry and can be successfully used as substrates in AD protocols, in the presence of tailored, selective, easily tunable and thermally ...
Sylwia Kostera, Luca Gonsalvi
wiley +1 more source
A copper-dependent redox-based hydrogen peroxide perception in plants. [PDF]
Ishihama N +11 more
europepmc +1 more source

