Results 211 to 220 of about 95,737 (296)

Self‐Immolative Poly(Benzyl Ether)s: Design Principles and Controlled Depolymerization

open access: yesChemistry – A European Journal, EarlyView.
Unzipping to Sustainability: This Concept article explores the thermodynamic design of quinone‐methide (QM)‐based poly(benzyl ether)s (PBEs). It explains how a low ceiling temperature (Tc), QM stability, and an entropic gain drive rapid depolymerization (“unzipping”) of PBEs into monomers.
Ji Woo Kim, Yewon Kang, Hyungwoo Kim
wiley   +1 more source

From P-Type to Bipolar: A Quinone-Core Engineering Strategy in D-A-D Organic Cathodes for Ultra-Stable and High-Energy Organic Lithium-Ion Batteries. [PDF]

open access: yesAngew Chem Int Ed Engl
Wang X   +15 more
europepmc   +1 more source

Silver‐Mediated Deuterium Labelling of Quinones and Related Compounds by Hydrogen Isotope Exchange With D2O

open access: yesChemistry – A European Journal, EarlyView.
A new silver‐catalyzed H/D exchange reaction was developed for the labelling of quinones and related compounds. Both homogeneous and heterogeneous catalytic processes were implemented using heavy water as a simple deuterium source. The corresponding deuterated compounds were obtained with high isotopic enrichment through a practical method that opens ...
Joyce C. de Oliveira   +7 more
wiley   +1 more source

Machine learning-accelerated screening of hydroquinone analogs for proton-coupled electron transfer. [PDF]

open access: yesChem Sci
Sarma R   +8 more
europepmc   +1 more source

Redox‐Switchable Optical and Magnetic Properties in a Self‐Assembled Hexanuclear Ni(II) Double‐Decker Complex

open access: yesChemistry – A European Journal, EarlyView.
A triangular double‐decker Ni6 complex self‐assembles from Ni(II), TMEDA, and a triphenylene tris dioxolene non‐innocent ligand, with two face‐to‐face tris‐semiquinone decks held by a strong covalent C─C interaction. This rigid scaffold delivers four reversible ligand‐centered redox events: oxidation switches on an intense near‐infrared band and ...
Aristide Colin   +12 more
wiley   +1 more source

Hydrogen Release From Silicon─Hydrogen Systems: From Surface Chemistry to Higher‐Coordinate Molecular Mechanisms

open access: yesChemistry – A European Journal, EarlyView.
Hydrogen‐release processes in silicon chemistry occur across a broad spectrum of systems, including crystalline silicon surfaces, nanoporous materials, Zintl phases, and molecular hydrides. This Review highlights how Si─H activation and H2 evolution are governed by structure, coordination environment, and dynamic access to reactive geometries, with ...
Robin Rothfelder, Jonathan O. Bauer
wiley   +1 more source

Designing Threefold π‐Surfaces Through Peripheral Halogenation to Shape Multidirectional Molecular Packing

open access: yesChemistry – A European Journal, EarlyView.
The complete series of hexahalogenated triptycene‐tribenzoquinones, comprising newly synthesized fluoro‐, bromo‐, and iodo‐substituted derivatives together with the previously reported chloro analogue, enables systematic comparison of their molecular properties and intermolecular interactions in relation to their crystal packing modes.
Shuta Tsuruga   +4 more
wiley   +1 more source

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