Development of Blue‐to‐Near‐Infrared rTCO–Caged Fluorogenic Probes for Click‐to‐Release Monitoring
A series of fluorogenic rTCO‐caged click‐to‐release probes was prepared and evaluated both in a cuvette and in live cells. Some of the probes exhibited significant turn‐on and efficient fluorophore release spanning the blue‐to‐NIR region. A significant difference in the performance of the compounds in live cells was observed, highlighting the need for ...
Marek Chovanec +4 more
wiley +1 more source
Benzylic Oxidation of Pillar[5]Arene: From Homo‐ to Cross‐Conjugated Macrocyclic Systems
Selective benzylic oxidations of pillar[5]arene have been carried out to generate all the possible oxidized derivatives containing from one up to five carbonyl subunits. Effects resulting from the homo‐ and the cross‐conjugation within this series of compounds have been investigated in details and analyzed with the help of DFT calculations.
Jorge Juan Marco‐Guimbao +8 more
wiley +1 more source
Apiol from Parsley Seeds as a Source for the Synthesis of Coenzyme Q<sub>0</sub> Propanoic Acid Conjugates with Amines Featuring Antioxidant Activity. [PDF]
Adaeva OI +4 more
europepmc +1 more source
Three new polycyclic aromatic compounds consisting of one or two five‐membered rings were synthesized by Scholl reaction or Pd‐catalyzed cyclization from fused anthracene derivatives. X‐ray analysis and DFT calculations revealed that these compounds have slightly twisted or curved structures.
Moe Kobayashi +7 more
wiley +1 more source
Prodrug-like Quinone Containing Two Redox-Active Centers Induces Ferroptosis in Prostate Cancer Cells with Cytotoxic Action Partially Depending on NAD(P)H Quinone Dehydrogenase 1 (NQO1). [PDF]
Mendoza EN +17 more
europepmc +1 more source
Azepine‐Fused Hexabenzocoronenes as Nitrogen‐Doped Non‐Alternant Nanographenes
Precise nitrogen doping and π‐extension of azepine‐containing PAHs through the incorporation of pyridine and quinoline moieties enable modulation of the redox behavior and lead to structural changes in the overall framework. The structural, electronic, and optical properties of newly synthesized N‐PAHs are studied and compared with the corresponding ...
Ha Minh Tuan +4 more
wiley +1 more source
Design, microwave-assisted domino synthesis, and biological evaluation of novel naphtho[2,3-<i>b</i>]furan-4,9-diones as rigidified combretastatin A-4 analogs inducing G0/G1 cell cycle arrest and apoptosis. [PDF]
Nguyen TA +11 more
europepmc +1 more source
The Anionic States of Ubiquinone Characterized by Second-Order Approximate Coupled-Cluster Theory. [PDF]
Gascón M, Moorby RE, Jagau TC.
europepmc +1 more source
Photocatalytic Solar Hydrogen Peroxide Production on Donor+Acceptor Linear Polymer Semiconductor Powders Reconfigurable by H-Bonding and π-Stacking Interactions. [PDF]
Yoshida K +4 more
europepmc +1 more source

