Results 91 to 100 of about 113,489 (369)

On dithiothreitol (DTT) as a measure of oxidative potential for ambient particles: evidence for the importance of soluble ewline transition metals [PDF]

open access: yesAtmospheric Chemistry and Physics, 2012
The rate of consumption of dithiothreitol (DTT) is increasingly used to measure the oxidative potential of particulate matter (PM), which has been linked to the adverse health effects of PM. While several quinones are known to be very reactive in the DTT
J. G. Charrier, C. Anastasio
doaj   +1 more source

The Effect of Water on Quinone Redox Mediators in Non- aqueous Li-O2 Batteries [PDF]

open access: yesarXiv, 2018
The parasitic reactions associated with reduced oxygen species and the difficulty in achieving the high theoretical capacity have been major issues plaguing development of practical non-aqueous Li-O2 batteries. We hereby address the above issues by exploring the synergistic effect of 2,5-di-tert-butyl-1,4- benzoquinone and H2O on the oxygen chemistry ...
arxiv  

Organocatalytic synthesis of axially chiral atropisomers [PDF]

open access: yes, 2017
This review summarises the recent progress made in the organocatalytic synthesis of atropisomeric compounds. Methodologies based on dynamic kinetic resolution and direct access to BINOL-like biaryls are described.
Renzi, P.
core   +1 more source

Antioxidant and Anti‐Senescence Polyvinyl Alcohol‐Gallic Acid Supramolecular Hydrogels for Stem Cell Culture

open access: yesAdvanced Healthcare Materials, EarlyView.
The PVA‐GA hydrogel is formed through hydrogen bonding between PVA hydroxyl groups and GA galloyl units, enabling sustainable GA release and its extended biological activity. The hydrogel scavenges ROS to reduce oxidative stress, preventing mitochondrial damage from excessive ROS, mitigating hADSC senescence, and preserving VEGF secretion, offering a ...
Yiduo Zhou   +11 more
wiley   +1 more source

Ir(III)-Naphthoquinone complex as a platform for photocatalytic activity

open access: yesJournal of Photochemistry and Photobiology, 2022
Inspired by the primary events that take place in Photosystem II (PSII), we designed and synthesized a heteroleptic Ir(III) complex featuring an attached naphthoquinone (NQ) as an electron transfer (ET) auxiliary reminiscent of the plastoquinone electron
Walter D. Guerra   +7 more
doaj  

Experimental and Theoretical Reduction Potentials of Some Biologically Active ortho-Carbonyl para-Quinones

open access: yesMolecules, 2017
The rational design of quinones with specific redox properties is an issue of great interest because of their applications in pharmaceutical and material sciences.
Maximiliano Martínez-Cifuentes   +4 more
doaj   +1 more source

The simulation of interquinone charge transfer in a bacterial photoreaction center highlights the central role of a hydrogen-bonded non-heme iron complex [PDF]

open access: yes, 1954
We consider electron transfer between the quinones QA and QB, one of the final steps in the photoinduced charge separation in the photoreaction center of Rhodobacter sphaeroides.
Burggraf, Fabian, Koslowski, Thorsten
core   +3 more sources

Direct Surface Modification of the Epidermis Using Mussel‐Inspired Polydopamine with Multiple Anti‐Biofouling Functions

open access: yesAdvanced Healthcare Materials, EarlyView.
Surface modification using mussel‐derived polydopamine (PDA) is a versatile and robust biocompatible strategy that enables direct application to various epidermal surfaces, regardless of their morphological complexity or surface characteristics. The PDA‐coated epidermis exhibits multiple anti‐biofouling functionalities, including antibacterial and anti‐
Su Eon Lee   +14 more
wiley   +1 more source

THz-Raman Identification of labile products in the system "phenol-semiquinone-quinone" [PDF]

open access: yesarXiv, 2016
The paper presents the results of SERS studies of the dynamic behavior of "phenol-semiquinone-quinone" system. This system is a key part of chemiluminescent sensors for reactive oxygen species. The dynamics of the system seems to be very important in the processes that determine the secondary metabolism at the cellular level in molecular biology.
arxiv  

Site of biosynthesis of a-tocopherol in spinach chloroplasts [PDF]

open access: yes, 1980
The chloroplast envelope is a continuous boundary of two osmiophilic membranes and has an important role in galactolipid synthesis [ 11.
Bickel   +18 more
core   +1 more source

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