Results 91 to 100 of about 113,489 (369)
On dithiothreitol (DTT) as a measure of oxidative potential for ambient particles: evidence for the importance of soluble ewline transition metals [PDF]
The rate of consumption of dithiothreitol (DTT) is increasingly used to measure the oxidative potential of particulate matter (PM), which has been linked to the adverse health effects of PM. While several quinones are known to be very reactive in the DTT
J. G. Charrier, C. Anastasio
doaj +1 more source
The Effect of Water on Quinone Redox Mediators in Non- aqueous Li-O2 Batteries [PDF]
The parasitic reactions associated with reduced oxygen species and the difficulty in achieving the high theoretical capacity have been major issues plaguing development of practical non-aqueous Li-O2 batteries. We hereby address the above issues by exploring the synergistic effect of 2,5-di-tert-butyl-1,4- benzoquinone and H2O on the oxygen chemistry ...
arxiv
Organocatalytic synthesis of axially chiral atropisomers [PDF]
This review summarises the recent progress made in the organocatalytic synthesis of atropisomeric compounds. Methodologies based on dynamic kinetic resolution and direct access to BINOL-like biaryls are described.
Renzi, P.
core +1 more source
The PVA‐GA hydrogel is formed through hydrogen bonding between PVA hydroxyl groups and GA galloyl units, enabling sustainable GA release and its extended biological activity. The hydrogel scavenges ROS to reduce oxidative stress, preventing mitochondrial damage from excessive ROS, mitigating hADSC senescence, and preserving VEGF secretion, offering a ...
Yiduo Zhou+11 more
wiley +1 more source
Ir(III)-Naphthoquinone complex as a platform for photocatalytic activity
Inspired by the primary events that take place in Photosystem II (PSII), we designed and synthesized a heteroleptic Ir(III) complex featuring an attached naphthoquinone (NQ) as an electron transfer (ET) auxiliary reminiscent of the plastoquinone electron
Walter D. Guerra+7 more
doaj
The rational design of quinones with specific redox properties is an issue of great interest because of their applications in pharmaceutical and material sciences.
Maximiliano Martínez-Cifuentes+4 more
doaj +1 more source
The simulation of interquinone charge transfer in a bacterial photoreaction center highlights the central role of a hydrogen-bonded non-heme iron complex [PDF]
We consider electron transfer between the quinones QA and QB, one of the final steps in the photoinduced charge separation in the photoreaction center of Rhodobacter sphaeroides.
Burggraf, Fabian, Koslowski, Thorsten
core +3 more sources
Surface modification using mussel‐derived polydopamine (PDA) is a versatile and robust biocompatible strategy that enables direct application to various epidermal surfaces, regardless of their morphological complexity or surface characteristics. The PDA‐coated epidermis exhibits multiple anti‐biofouling functionalities, including antibacterial and anti‐
Su Eon Lee+14 more
wiley +1 more source
THz-Raman Identification of labile products in the system "phenol-semiquinone-quinone" [PDF]
The paper presents the results of SERS studies of the dynamic behavior of "phenol-semiquinone-quinone" system. This system is a key part of chemiluminescent sensors for reactive oxygen species. The dynamics of the system seems to be very important in the processes that determine the secondary metabolism at the cellular level in molecular biology.
arxiv
Site of biosynthesis of a-tocopherol in spinach chloroplasts [PDF]
The chloroplast envelope is a continuous boundary of two osmiophilic membranes and has an important role in galactolipid synthesis [ 11.
Bickel+18 more
core +1 more source