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Alkynyl- and dialkynyl-quinoxalines. Synthesis of condensed quinoxalines

Journal of the Chemical Society, Perkin Transactions 1, 1980
Condensation of 2-chloro- and 2,3-dichloro-quinoxalines with alk-1-ynes in the presence of bis(triphenylphosphine)palladium(II) dichloride and copper(I) iodide gives mono- and di-alkynylquinoxalines. Addition of amines to these products gives stable enamines; hydration gives 2′-oxoalkyl compounds which exist predominantly in the intramolecularly ...
M. Ismail Brohi, Donald E. Ames
openaire   +2 more sources

Photoinduced Cyclizations of o-Diisocyanoarenes with Organic Diselenides and Thiols that Afford Chalcogenated Quinoxalines.

Journal of Organic Chemistry, 2020
This study describes the syntheses of 2,3-bis(selanyl)quinoxalines via the photoinduced cyclizations of o-diisocyanoarenes with diaryl or dialkyl diselenides, in addition to providing a detailed discussion of the corresponding mechanism, and revealing ...
Cong Chi Tran   +4 more
semanticscholar   +1 more source

NaOH-Mediated Direct Synthesis of Quinoxalines from o-Nitroanilines and Alcohols via a Hydrogen-Transfer Strategy.

Journal of Organic Chemistry, 2020
A NaOH-mediated sustainable synthesis of functionalized quinoxalines is disclosed via redox condensation of o-nitroamines with diols and α-hydroxy ketones.
Yan-Bing Wang   +8 more
semanticscholar   +1 more source

Direct Synthesis of Pyrrolo[1,2-α]quinoxalines via Iron-Catalyzed Transfer Hydrogenation between 1-(2-Nitrophenyl)pyrroles and Alcohols.

Journal of Organic Chemistry, 2020
Herein, we describe novel iron-catalyzed transfer hydrogenation between alcohols and 1-(2-nitrophenyl)pyrroles for the synthesis of pyrrolo[1,2-α]quinoxalines.
Simin Chun   +5 more
semanticscholar   +1 more source

Structures of quinoxaline antibiotics

Acta Crystallographica Section B Structural Science, 1995
The crystal structures of three quinoxaline antibiotics-echinomycin 2QN, triostin C and the C222(1) form of triostin A--have been determined, and the structure of the P2(1)2(1)2(1) form of triostin A has been re-refined against our previously reported data. The molecular conformations are compared with those deduced from NMR data and those reported for
Karen Schmidt-Bäse   +6 more
openaire   +3 more sources

Pyrrolo[1,2-a]quinoxalines based on quinoxalines (Review)

Chemistry of Heterocyclic Compounds, 2010
Published data on methods for the synthesis of pyrrolo[1,2-a]quinoxalines, based on derivatives of quinoxalines and also on compounds that are not initially derivatives of quinoxalines or pyrroles are summarized and classified.
Alexey A. Kalinin, Vakhid A. Mamedov
openaire   +2 more sources

Hydrogen Auto‐transfer Synthesis of Quinoxalines from o‐Nitroanilines and Biomass‐based Diols Catalyzed by MOF‐derived N,P Co‐doped Cobalt Catalysts

, 2020
A Co‐based heterogeneous catalyst supported on N,P co‐doped porous carbon (Co@NCP) is prepared via a facile in‐situ doping‐carbonization method. The Co@NCP composite features a large surface area, high pore volume, high‐density and strong basic sites ...
K. Sun, Dan-Dan Li, Guo-ping Lu, C. Cai
semanticscholar   +1 more source

Quinoxaline-Bridged Porphyrinoids

Journal of the American Chemical Society, 2002
Quinoxaline-bridged porphyrinoids (3), the first macrocycles containing dipyrrolylquinoxaline (DPQ, 1) subunits, were synthesized from the condensation of the diformyl-substituted DPQ derivatives (2) and 1,8-diaminoanthracene. The resulting structures were confirmed by X-ray analyses, which showed encapsulation of CHCl(3) molecules within the columnar ...
Hiroyuki Furuta   +6 more
openaire   +3 more sources

Synthesis of fused quinoxalines

Mendeleev Communications, 2002
AbstractFor Abstract see ChemInform Abstract in Full Text.
Mikhail I. Kodess   +4 more
openaire   +3 more sources

Visible-light induced phosphonation of quinoxalines and quinoxalin-2(1H)-ones under aerobic metal-free conditions

, 2020
Phosphonation of quinoxalines and quinoxalin-2(1H)-ones utilizing aerobic oxygen as green oxidant under visible light conditions at room temperature has been described.
D. Rawat, Rahul Kumar, A. Subbarayappa
semanticscholar   +1 more source

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