Results 11 to 20 of about 89,874 (280)
Lipase catalysed kinetic resolution of racemic 1,2-diols containing a chiral quaternary center [PDF]
Optically active 1,2-diols are valuable buildings blocks in organic synthesis. In the present paper, a set of racemic 1,2-diols with an ester functional group are prepared, starting from -ketoesters in a three-step procedure with moderate yields.
Gonzalo Calvo, Gonzalo de
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Background: This study investigated the effect of combining oral dexamethasone with either nebulized racemic epinephrine or salbutamol compared to bronchodilators alone for the treatment of infants with bronchiolitis.
Manal Bawazeer +7 more
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Racemic DNA Crystallography [PDF]
AbstractRacemates increase the chances of crystallization by allowing molecular contacts to be formed in a greater number of ways. With the advent of protein synthesis, the production of protein racemates and racemicāprotein crystallography are now possible.
Pradeep K. Mandal +3 more
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Lattice and thermodynamic characteristics of N-stearoyl-allo-threonine monolayers
The effect of the second chiral center of diastereomeric N-alkanoyl-allo-threonine on the main monolayer characteristics has been investigated. The characteristic features of the enantiomeric and racemic forms of N-stearoyl-allo-threonine monolayers are ...
Brezesinski, G. +2 more
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Spatial dynamics of homochiralization [PDF]
The emergence and spreading of chirality on the early Earth is considered by studying a set of reaction-diffusion equations based on a polymerization model.
Brandenburg, Axel, Multamaki, Tuomas
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Uni-directional polymerization leading to homochirality in the RNA world [PDF]
The differences between uni-directional and bi-directional polymerization are considered. The uni-directional case is discussed in the framework of the RNA world. Similar to earlier models of this type, where polymerization was assumed to proceed in a bi-
Andersen, A. C. +3 more
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Racemic tricarbonyl[7-methoxy-2-(η6-phenyl)chromane]chromium(0)
In the title compound, [Cr(C16H16O2)(CO)3], the Cr0 atom of the Cr(CO)3 unit is coordinated to the phenyl ring of the flavan ligand in an η6 mode, with a normal arene-to-metal distance.
Mukut Gohain +2 more
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Synthesis of racemic and chiral BEDT-TTF derivatives possessing hydroxy groups and their achiral and chiral charge transfer complexes [PDF]
Chiral molecular crystals built up by chiral molecules without inversion centers have attracted much interest owing to their versatile functionalities related to optical, magnetic, and electrical properties.
Hashimoto, C +6 more
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Racemic tricarbonyl[(4a,5,6,7,8,8a-η)-2-phenyl-3,4-dihydro-2H-1-benzopyran]chromium(0)
The title compound, [Cr(C15H14O)(CO)3], displays a distorted envelope configuration of the dihydropyrane ring. The dihedral angle between the phenyl and phenylene rings is 50.63 (4)°.
Johannes H. van Tonder +2 more
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Phase chirality and stereo-selective swelling of cholesteric elastomers [PDF]
Cholesteric elastomers possess a macroscopic ``phase chirality'' as the director n rotates in a helical fashion along an optical axis $z$ and can be described by a chiral order parameter.
A. R. Tajbakhsh +18 more
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