Results 61 to 70 of about 89,874 (280)
Synthese von (all-E,14S)-14,15-Epoxy-14,15-dihydrogeranylgeranial und 1,2-Epoxy-1,2-dihydrophytoen
CHIMIA, 1986 The first synthesis of the optically active geranylgeranial oxide (S)-1 starting from D-mannitol including a sulfone coupling reaction as the key step is reported.
Christoph Arm +2 more
doaj +1 more source
Biocatalytic preparation and absolute configuration of enantiomerically pure fungistatic anti-2-benzylindane derivatives. Study of the detoxification mechanism by Botrytis cinerea [PDF]
, 2010 Enantiomerically pure 2-benzylindane derivatives were prepared using biocatalytic methods and their absolute configuration determined. (1R,2S)-2-Benzylindan-1-ol ((1R,2S)-2) and (S)-2-benzylindan-1-one ((S)-3) were produced by fermenting baker’s yeast.
Aleu +23 more
core +2 more sources
Space Group Modulated Upconversion and Mechanoluminescence in [YbEu] Cocrystal Complexes
Advanced Optical Materials, EarlyView.We report here a space group regulation strategy to optimize both upconversion and mechanoluminescence in cocrystal assemblies, representing the first example of integrating these two properties within a single lanthanide complex material. ABSTRACT Lanthanide complexes exhibiting stimuli‐responsive luminescence, such as upconversion (UC) and ...
Wei Sun +9 more
wiley +1 more source
Total Synthesis of the Spirocyclic Bis‐Indole Alkaloid (−)‐Owerreine via a [4+2] Annulation
Angewandte Chemie, EarlyView.The total synthesis of the bis‐indole alkaloid (−)‐owerreine has been accomplished by a diastereoselective [4+2] annulation between an enamine and an α,β−unsaturated indolenine precursor to form the 3‐spirocyclic tetrahydropyridine linkage of the natural product. DFT calculations allow an understanding of the mechanism of the key annulation.
Elisa Coll +4 more
wiley +2 more sources
Synthesis of New Medium- and Large- Sized Racemic and Chiral Lactones
Journal of the Turkish Chemical Society, Section A: Chemistry, 2018 Successive reaction of long chain w-1, w-2, w-4 and w-5 hydroxycarboxylic acids 1a-1e with a cyanuric chloride (CC) and triethylamine afforded the corresponding racemic lactones 2a-2e in high yields.
Hasniye Yaşa +1 more
doaj +1 more source
Chiral molecule adsorption on helical polymers [PDF]
, 2003 We present a lattice model for helicity induction on an optically inactive polymer due to the adsorption of exogenous chiral amine molecules. The system is mapped onto a one-dimensional Ising model characterized by an on-site polymer helicity variable ...
A. Teramoto +16 more
core +1 more source
Advanced Science, EarlyView.This study presents the de novo design and directed evolution of a mirror‐image D‐protein inhibitor targeting human interleukin‐4 (IL‐4). The engineered molecule exhibits nanomolar binding affinity for IL‐4 and effectively inhibits IL‐4–mediated signaling.
Liqing Xu +7 more
wiley +1 more source
Angewandte Chemie, EarlyView.A NiH‐catalyzed α‐alkenylation via Markovnikov hydronickellation of alkynes enables convenient access to α‐chrial β‐methylene carbonyl frameworks that are prevalent in biorelevant molecules. High regio‐ and enantioselectivities have been achieved with excellent functional group tolerance and applicability toward complex structures. The β‐methylene unit
Hyeontaek Nam +3 more
wiley +2 more sources
Advanced Science, EarlyView.ABSTRACT Inositol pyrophosphates (PP‐InsPs) are central regulators of eukaryotic signaling events. While certain PP‐InsP isomers have been conclusively linked to the regulation of phosphate homeostasis through interaction with SPX domain‐containing proteins in plants, the functions of the recently discovered isomer 4/6‐PP‐InsP5 remain largely unknown ...
Kevin Ritter +10 more
wiley +1 more source
Angewandte Chemie, EarlyView.Rh‐catalyzed chemodivergent parallel kinetic resolution of racemic 1,6‐enynes with α‐fluoroacrylamides or mixtures of different acrylamides proceeded via [2+2+2] cycloaddition and C–H alkylation to afford structurally and stereochemically distinct products with high selectivity under mild conditions.
Shintaro Hamada +5 more
wiley +2 more sources