Results 41 to 50 of about 3,131,133 (230)

3-(2-Amino-1-methyl-4-oxo-4,5-dihydro-1H-imidazol-5-yl)-3-hydroxy-1-phenylindolin-2-one ethanol solvate

open access: yesActa Crystallographica Section E, 2009
In the title compound, C18H16N4O3·C2H5OH, molecules are linked into chains by a series of intermolecular N—H...O, N—H...N and O—H...O hydrogen bonds which stabilize the crystal structure.
Narsimha Reddy Penthala   +3 more
doaj   +1 more source

Racemic compound and conglomerate of anhydrous sibutramine hydrochloride: a rare case of relative stability

open access: yes, 2016
The thermal behaviours of racemic sibutramine hydrochloride monohydrate as well as that of the anhydrous state were investigated by DSC. A new anhydrous solid was then put in evidence and its crystal structure was solved from XRPD data.
F. Rosa, P. Négrier, P. Espeau
semanticscholar   +1 more source

Synthesis of Optically Active Bifunctional Building Blocks through Enantioselective Copper-Catalyzed Allylic Alkylation Using Grignard Reagents [PDF]

open access: yes, 2007
Enantioselective copper-catalyzed allylic alkylations were performed on allylic bromides with a protected hydroxyl or amine functional group using several Grignard reagents and Taniaphos L1 as a ligand.
Feringa, Ben L.,   +3 more
core   +1 more source

Non-Linear Effects in Asymmetric Reactions: Negative and Positive Stereoselectivity in the Formation of Homoleptic 1:2 Metal to Ligand Complexes of Chiral 1,9-Disubstituted Semicorrin Ligands

open access: yesCHIMIA, 2003
The stereoselectivity of the formation of bis-chelates with the 1,9-disubstituted chiral semicorrin ligands (1S,9S)-dimethyl 5-cyanosemicorrin-1,9-dicarboxylate (1) for Co2+, Ni2+, Cu2+, and Pd2+ and with its (1S,9S)-diethyl analogue 2 for Co2+
Nathalie Guicher   +2 more
doaj   +1 more source

(±)-Gossypol induces apoptosis and autophagy in head and neck carcinoma cell lines and inhibits the growth of transplanted salivary gland cancer cells in BALB/c mice [PDF]

open access: yes, 2016
Racemic Gossypol [(±)-GOS], composed of both (-)-GOS and (+)-GOS, is a small BH3-mimetic polyphenol derived from cotton seeds. (±)-GOS has been employed and well tolerated by cancer patients. Head and neck carcinoma (HNC) represents one of the most fatal
Andracchio, Orlando   +10 more
core   +1 more source

(3aR*,7aS*)-1-(p-Tolylsulfonyl)perhydroindol-2-one

open access: yesActa Crystallographica Section E, 2010
In the racemic title compound, C15H19NO3S, the dihedral angle between the planes of the benzene ring and the O=S=O group is 56.92 (7)° and the cyclohexane ring adopts a chair conformation.
Lei Fang, Xu-Bin Fang, Lei Chen
doaj   +1 more source

Synthesis and crystal structure of (±)-Goniotamirenone C

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2020
The structure of the racemic version of the natural product Goniotamirenone C [racemic anti-6-(2-chloro-1-hydroxy-2-phenylethyl)-2H-pyran-2-one, C13H11ClO3] at 150 K is reported. The compound crystallizes with monoclinic (P21/n) symmetry and with Z′ = 2.
Pornphimol Meesakul   +3 more
doaj   +1 more source

Phase Diagrams For The Blue Phases Of Highly Chiral Liquid Crystals [PDF]

open access: yes, 1993
Polarizing microscopy and optical-activity measurements are used to determine the phase diagram for the blue phases of chiral-racemic mixtures of terephthaloyloxy-bis-4-(2\u27-methylbutyl) benzoate.
Booth, C. J.   +3 more
core   +2 more sources

3,3,6-Tribromo-1-methyl-1H-2,1-benzothiazin-4(3H)-one 2,2-dioxide

open access: yesActa Crystallographica Section E, 2010
In the title compound, C9H6Br3NO3S, a halogenated benzothiazine derivative, the thiazine ring adopts a sofa conformation. The crystal studied was a racemic twin with a contribution of 72 (1)% of the major domain.
Ghulam Mustafa   +3 more
doaj   +1 more source

Expected and Unexpected Products in Half Curcuminoid Synthesis: Crystal Structures of But-3-en-2-ones and 3-Methylcyclohex-2-enones

open access: yesCrystals, 2021
The expected (E)-but-3-en-2-ones compounds I and II (half curcuminoids) were obtained by the Claisen–Schmidt reaction between aldehydes 3,4-dimethoxybenzaldehyde or 4-nitrobenzaldehyde with acetone.
Marco A. Obregón-Mendoza   +7 more
doaj   +1 more source

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