Results 31 to 40 of about 3,002,287 (282)
Beilstein Journal of Organic Chemistry, 2013 The intramolecular radical addition to aniline derivatives was investigated by DFT calculations. The computational methods were benchmarked by comparing the calculated values of the rate constant for the 5-exo cyclization of the hexenyl radical with the ...
Andreas Gansäuer +4 more
doaj +1 more source
Two-Step Azidoalkenylation of Terminal Alkenes Using Iodomethyl Sulfones
Molecules, 2019 The radical azidoalkylation of alkenes that was initially developed with α-iodoesters and α-iodoketones was extended to other activated iodomethyl derivatives.
Nicolas Millius +2 more
doaj +1 more source
Mekanisme Teoritis Pembentukan Senyawa Siklik Hidrokarbon dari Reaksi C4H5 dan C4H2
Indonesian Journal of Chemical Research, 2020 Acetylene and polyyne are intermediates in the formation of Polycyclic Aromatic Hydrocarbons (PAHs) and soot in combustion or pyrolysis. PAH formation from acetylene is known as the most adopted pathway because it has a low reaction energy.
Antonius Indarto, Lienda Handojo
doaj +1 more source
Pediatric Idiopathic Multicentric Castleman Disease Is Often Severe But Responsive to Siltuximab
Pediatric Blood &Cancer, EarlyView.ABSTRACT Background Idiopathic multicentric Castleman disease (iMCD) is a potentially fatal immunologic disorder marked by widespread lymphadenopathy and inflammation. Siltuximab, an interleukin‐6 (IL‐6) inhibitor, is the only FDA‐approved treatment for adult patients with iMCD.
Bridget Austin +17 more
wiley +1 more source
Pediatric Blood &Cancer, EarlyView.ABSTRACT Relapsed and/or refractory (R/R) pediatric acute leukemia carries a dismal prognosis, largely driven by chemoresistance to conventional salvage therapy. The BH3‐mimetic venetoclax, combined with chemotherapy or hypomethylating agents, has demonstrated efficacy in small clinical trials.
Katherine S. Colman +9 more
wiley +1 more source
, 2018 Suzuki–Miyaura couplings of tertiary-alkyl moieties are accomplished in the presence of a copper catalyst, in which quaternary carbons possessing various functional groups can be synthesized via a radical reaction.
Kimiaki Nakamura (1725316) +3 more
core +2 more sources
Pediatric Blood &Cancer, EarlyView.ABSTRACT Background Latino children are projected to make up nearly one‐third of United States (US) children by 2060, and many of their caregivers speak Spanish. Prior survey research has documented communication difficulties for Spanish‐speaking caregivers of children with cancer, but contemporary qualitative data are limited.
Jenny Ruiz +6 more
wiley +1 more source
Unimolecular reaction chemistry of a charge-tagged beta-hydroxyperoxyl radical [PDF]
, 2014 β-Hydroxyperoxyl radicals are formed during atmospheric oxidation of unsaturated volatile organic compounds such as isoprene. They are intermediates in the combustion of alcohols.
da Silva, Gabriel +5 more
core +1 more source
Iron(II)-catalyzed trifluoromethylation of vinylcyclopropanes
上海师范大学学报. 自然科学版, 2016 An efficient iron(II)-catalyzed trifluoromethylation of vinylcyclopropanes was developed.A series of CF3-containing dihydronaphthalene derivatives were prepared with a moderate to high yield.This method offers several advantages in terms of its mild ...
LI Zongrui, DENG Qinghai
doaj +1 more source
Density functional theory studies on the oleic acid thermal oxidation into volatile compounds
Food Chemistry: X, 2023 Oleic acid oxidation is one of the main sources of food flavor compounds. Volatile profiling was investigated using thermal desorption cryo-trapping combined with gas chromatography–mass spectrometry to analyze the volatile composition of oleic acid ...
Lin Xiao +9 more
doaj +1 more source