Gels, 2023 Although biodegradable microgels represent a useful drug delivery system, questions remain regarding the kinetics of gel degradation and subsequent drug release.
Iris G. Mercer +4 more
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Optimization and a Kinetic Study on the Acidic Hydrolysis of Dialkyl α-Hydroxybenzylphosphonates
Molecules, 2020 The two-step acidic hydrolysis of α-hydroxybenzylphosphonates and a few related derivatives was monitored in order to determine the kinetics and to map the reactivity of the differently substituted phosphonates in hydrolysis.
Nikoletta Harsági +4 more
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Effects of solvent and structure on the reactivity of 6-substituted nicotinic acids with diazodiphenylmethane in aprotic solvents [PDF]
Journal of the Serbian Chemical Society, 2009 The rate constants for the reactions of diazodiphenylmethane (DDM) with 6-substituted nicotinic acids in aprotic solvents at 30°C were determined. The obtained second order rate constants in aprotic solvents, together with literature data for benzoic and
Drmanić Saša Ž. +2 more
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Substituent and structural effects on the kinetics of the reaction of N-(substituted phenylmethylene)-m- and -p-aminobenzoic acids with diazodiphenylmethane [PDF]
Journal of the Serbian Chemical Society, 2007 The rate constants for the reaction of twenty-two N-(substituted phenyl methylene)-m- and -p-aminobenzoic acids with diazodiphenylmethane were determined in absolute ethanol at 30 °C.
BRATISLAV Z. JOVANOVIC +3 more
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Theoretical study of the addition and hydrogen abstraction reactions of the methyl radical with formaldehyde and hydroxymethylene [PDF]
Journal of the Serbian Chemical Society, 2018 The mechanism, thermochemistry and kinetics of the addition and hydrogen-atom abstraction reactions of the methyl radical with formaldehyde and hydroxymethylene were investigated by ab initio calculations.
Nguyen Huu Tho, Nguyen Xuan Sang
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, 2022 In the present work, we investigate how nuclear quantum effects modify the temperature dependent rate constants and, consequently, the activation energies in unimolecular reactions.
Simon, Huppert +2 more
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Frontiers in Chemistry, 2019 A full dimensional Potential Energy Surface (PES) of the CO + N2 system has been generated by extending an approach already reported in the literature and applied to N2-N2 (Cappelletti et al., 2008), CO2-CO2 (Bartolomei et al., 2012), and CO2-N2 ...
Andrea Lombardi +7 more
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Theoretical Determination of Rate Constants from Excited-States: Application to Benzophenone
, 2021 A cost-effective method of theoretically predicting electronic transition rate constants from the excited-states of molecules is reported. This method is based on density functional theory calculations of electronic states and quantitative rate constant ...
Hironori, Kaji, Katsuyuki, Shizu
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Influence of the acidity of the Iodous acid solution system on the kinetics of the disproportionation reaction [PDF]
Bulletin of Natural Sciences Research, 2021 Influence of the acidity of the iodous acid (HOIO) solution system on the kinetics disproportionation reaction is examined in aqueous sulfuric acid solution (0.125 moldm-3).
Marković Smiljana
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Investigation of the reactivity of 4-pyrimidinecarboxylic, 6-hydroxy-4-pyrimidinecarboxylic and 5-hydroxyorotic acids with diazodiphenylmethane in various alcohols. Part III [PDF]
Journal of the Serbian Chemical Society, 2007 Rate constants for the reaction of diazodiphenylmethane (DDM) with 4-pyrimidinecarboxylic, 6-hydroxy-4-pyrimidinecarboxylic and 5-hydroxyorotic acids were determined in twelve protic solvents at 30 °C using the well known UV-spectrophotometric method ...
FATHI H. ASSALEH +3 more
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