Results 151 to 160 of about 39,326 (254)

A New Switchable Zr12 Oxocluster Based Large Pore Metal–Organic Framework Functionalized With Spin Crossover Complexes for Acetic Acid Colorimetric Sensing

Angewandte Chemie, EarlyView.
We present here (1)⊂MIP‐216(Zr), a new hybrid material composed of an FeII spin crossover complex (1) loaded in the pores of a new hydrophobic metal–organic framework (MIP‐216(Zr), that presents a high affinity toward acetic acid and acts as a highly sensitive colorimetric sensor of acetic acid vapor due to a spin state switching of the encapsulated ...
Emmelyne Cuza, Chenchen Cao, Abeer Mohtar, Mohammad Wahiduzzaman, William Shepard, Guillaume Maurin, Moises L. Pinto, Christian Serre, Antoine Tissot   +8 more
wiley   +2 more sources

Mechanochemical synthesis of bis-benzoquinonylmethanes promoted by sulfonic acid-functionalized chitosan. [PDF]

RSC Adv
de Jesus IS, de Pontes JB, Gomes Gonzaga DT, de Carvalho da Silva F, Ferreira VF.   +4 more
europepmc   +1 more source

Activity of ice-binding proteins can be markedly enhanced by protein tags.

Nanoscale
van den Broek D, Giezen SN, Hogervorst TP, de Vries R, Voets IK.   +4 more
europepmc   +1 more source

Evolutions in Microstructure and Properties of Cu-Ni-Si-Mg-Mn Multi-Element High-Solute Alloy During a Short-Time Solid Solution Treatment, Aging, and Cold-Rolling. [PDF]

Materials (Basel)
Zhang Y, Feng X, Zhang Q, Lu X, Xu C, Zhang X, Liu F, Song Z.   +7 more
europepmc   +1 more source

Copper(II/III) Redox Couple Enables C─H Methylation via a Radical Mechanism Analogous to SAM Enzymes

Angewandte Chemie, EarlyView.
Biological C–H methylation proceeds through radical pathways mediated by one‐electron redox cofactors, yet no synthetic model has reproduced this reactivity. Here, we report the first isolable Cu(II/III)–methyl complexes that mediate C–H methylation through hydrogen atom transfer and methyl radical rebound.
Emily N. Doss, Curtis E. Moore, Shiyu Zhang   +2 more
wiley   +2 more sources

Constitutive behaviour and microstructural evolution in thermally deformed Al-Zn-Mg alloy. [PDF]

Sci Rep
Harikrishna K, Nithin A, Manohar G, Nagaraju KVV, Bukate BB, Bhowmik A.   +5 more
europepmc   +1 more source

Silicon‐Bridged Homocyclopentadienides: Metal‐Assisted Facile Ring Expansion of Cyclopentadienide by Transient Imino(Metallophosphino)Silylenes

Angewandte Chemie, EarlyView.
We demonstrate the facile aromatic C─C bond cleavage of cyclopentadienide mediated by transient imino(metallophosphino)silylenes, enabling the transformation of an aromatic system into a homoaromatic species. The steric bulk of the phosphino substituent, together with the weak interaction between the coinage metal and the cyclopentadienide ligand, are ...
Huaiyuan Zhu, Xufang Liu, Shicheng Dong, Jun Zhu, Shigeyoshi Inoue   +4 more
wiley   +2 more sources

Mechanistic Insights Into Color and Texture Stability of Frozen Tropical Vegetables: Processing, Modeling, and Preservation Strategies. [PDF]

Food Sci Nutr
Mahmud MM, Mia MS, Nabi MHB, Arnab AH, Zzaman W.   +4 more
europepmc   +1 more source

Synthesis and One‐Electron Reduction of Donor‐Acceptor‐Stabilized SiII–EII–SiII Trimetallylenes (E = Ge, Sn, Pb)

Angewandte Chemie, EarlyView.
The first isolable trimetallylenes (SiII)2EII (E = Ge, Sn, Pb) with pπ‐type silanylidenyl donors have been synthesized, having donor–acceptor electronic structures that give rise to near‐infrared absorption and enable access to bis(silanylidenyl)‐supported GeI and SnI radical anions upon one‐electron reduction with elemental potassium. ABSTRACT Herein,
Chaopeng Hu, Shenglai Yao, Christian Lorent, Matthias Driess   +3 more
wiley   +2 more sources

Study of the Influence of Thermomechanical Treatment on the Structure and Properties of Zircalloy-4 Alloy. [PDF]

Materials (Basel)
Popov F, Kawalek A, Ozhmegov K, Lutchenko N, Panin E, Lezhnev S, Arbuz A.   +6 more
europepmc   +1 more source