Results 141 to 150 of about 39,326 (254)

Supramolecular Protection–Deprotection for Switching Pore‐Surface Functionality in a Crystalline Porous Organic Salt

Angewandte Chemie, EarlyView.
A supramolecular protection–deprotection strategy temporally separates the framework construction from pore‐surface activation in a porous organic salt. In Form I, phenolic OH groups are protected by DMSO, enabling framework formation. Stepwise single‐crystal‐to‐single‐crystal phase transformation (SCSC) affords a dormant intermediate (Form II ...
Kazuki Shiga, Ryota Yamazaki, Hajime Shigemitsu, Yuuya Nagata, Norimitsu Tohnai   +4 more
wiley   +2 more sources

Simultaneous Electronic and Crystallographic Modulation of Cs3Bi2Br9 by Single‐Element Sn Substitution for Enhanced CO2 Photoreduction

Advanced Energy Materials, EarlyView.
Aliovalent B‐site substitution with Sn2+ in lead‐free perovskite, Cs3Bi2Br9, is employed to simultaneously induce lattice contraction and bromine vacancy through charge imbalance and ionic radius mismatch. The resulting structural distortion modulates the electronic structure and improves charge separation, leading to enhanced visible‐light‐driven CO2 ...
Justin Khor, Jiale Lee, Xin Ying Kong, Qixin Zhou, Yongfa Zhu, Jingxiang Low, Siang‐Piao Chai, Lling‐Lling Tan   +7 more
wiley   +1 more source

Selective Sequential Depolymerization of Mixed Plastics Mediated by Photothermal Conversion

Angewandte Chemie, EarlyView.
This work provides a selective sequential depolymerization strategy for mixed plastic waste. The method enables depolymerization of poly(L‐lactide), polystyrene, and poly(ethylene terephthalate), including their post‐consumer plastics. Without presorting, monomer separation is achieved by leveraging the distinct chemical reactivities of each polymer in
Yoon‐Jung Jang, Angela Milo, Deepika Shingwekar, Hanning Jiang, Erin E. Stache   +4 more
wiley   +2 more sources

Population balance modeling and digital design of degree of agglomeration in industrial crystallization

AIChE Journal, EarlyView.
Abstract This study presents a coupled population balance model (PBM) for describing the degree‐of‐agglomeration (DoA) in crystallization by independently tracking total particle and agglomerate number densities. Applied to an industrial active pharmaceutical ingredient, the model outperformed bridge‐counting methods and accurately captured DoA trends ...
Yung‐Shun Kang, Hemalatha Kilari, Neda Nazemifard, C. Benjamin Renner, Yihui Yang, Charles Papageorgiou, Zoltan K. Nagy   +6 more
wiley   +1 more source

Valency‐Controlled Multiphotochromism: Gated Switching and Photoswitchable Lewis Superacidity at Silicon

Angewandte Chemie, EarlyView.
Multiphotochromic switching is controlled by silicon valency in a diarylethene‐based molecular architecture. Lewis base coordination gates electronic communication between the photochromic units, thereby enabling selective access to distinct switching states.
Lennart Stoess, Valentin D. Hannibal, Lutz Greb   +2 more
wiley   +2 more sources

Metastable phase diagram, mobility, and kinetic stability of amorphous mixtures of two mutually compatible APIs. [PDF]

Int J Pharm X
Noor W, Romanini M, Villalobos L, Talukder B, Tamarit JL, Macovez R.   +5 more
europepmc   +1 more source

Bayesian Exploration of Metal‐Organic Framework‐Derived Nanocomposites for High‐Performance Supercapacitors

Advanced Intelligent Discovery, EarlyView.
An AI‐assisted approach is introduced to decode synthesis–performance relationships in metal‐organic framework‐derived supercapacitor materials using Bayesian optimization and predictive modeling, streamlining the search for optimal energy storage properties.
David Gryc, Pritam Banerjee, Felipe Jacques Lima Duarte, Joerg R. Jinschek, Premkumar Murugesan, Babak Rezaei, Stephan Sylvest Keller, Roland A. Fischer, Mian Zahid Hussain   +8 more
wiley   +1 more source

Charge‐Transfer Assembly of Electrically Conductive Metal–Organic Cages

Angewandte Chemie, EarlyView.
Electrically conductive and permanently porous metal–organic cages are realized using charge‐transfer assembly between electron‐donating cages and electron‐accepting molecules, which self‐assemble to create new charge transport pathways without sacrificing access to internal void space.
Kyungseop Lee, Sebastian M. Krajewski, Werner Kaminsky, Douglas A. Reed   +3 more
wiley   +2 more sources

Electroplastic Cyclic Deformation of CuZn30 Brass. [PDF]

Materials (Basel)
Weiler W, Jaśkiewicz K, Zimniak Z.
europepmc   +1 more source

Cage‐Type Porous Organic Salts as Ship‐in‐a‐Bottle Nanoreactors for Light‐Transparent and Reusable Molecular Photocatalysts

Angewandte Chemie, EarlyView.
Light‐transparent, cage‐type porous organic salts (POSs) function as nanoreactors that heterogenize molecularly defined photocatalysts through size exclusion. Photocatalysts are encapsulated intact during crystallization, providing confined yet accessible reaction fields under visible light without catalyst modification.
Kazuki Shiga, Ryosuke Nishikubo, Masafumi Minoshima, Akinori Saeki, Kazuya Kikuchi, Norimitsu Tohnai   +5 more
wiley   +2 more sources