Radical-mediated ring contraction in the biosynthesis of 7-deazapurines [PDF]
Pyrrolopyrimidine containing natural products are widely distributed in Nature. The biosynthesis of the 7-deazapurine moiety that is common to all pyrrolopyrimidines entails multiple steps, one of which is a complex radical-mediated ring contraction ...
Bandarian, Vahe, Drennan, Catherine L.
core +1 more source
Sol-Gel Heterogeneization of an Ir(III) Complex for Sustainable Visible-Light Redox Photocatalysis
Photocatalysis is a key strategy for the development of sustainable solar-driven chemical processes. In this work, we report the synthesis and characterization of a novel organometallo–ionosilica material derived from the self-condensation of an ...
Janira Herce +4 more
doaj +1 more source
Actions for improving water quality are critical and include the remediation of polluted groundwater. The effectiveness of the remediation strategy to remove contamination by chlorinated solvents may be increased by combining physicochemical treatments ...
Laura Lorini +5 more
doaj +1 more source
Mechanisms of bacterially catalyzed reductive dehalogenation [PDF]
Nine bacteria were tested for the ability to dehalogenate tetrachloromethane (CT), tetrachloroethene (PCE), and 1, 1, 1-trichloroethane (TCA) under anaerobic conditions. Three bacteria were able to reductively dehalogenate CT. Dehalogenation ability was not readily linked to a common metabolism or changes in culture redox potential.
openaire +1 more source
Benzoate-driven dehalogenation of chlorinated ethenes in microbial cultures from a contaminated aquifer [PDF]
Microbial dehalogenation of tetrachloroethene (PCE) and cis-dichloroethene (cis-DCE) was studied in cultures from a continuous stirred tank reactor initially inoculated with aquifer material from a PCE-contaminated site.
Bunge, Michael +6 more
core
Reductive Dehalogenation and Conversion of 2-Chlorophenol to 3-Chlorobenzoate in a Methanogenic Sediment Community: Implications for Predicting the Environmental Fate of Chlorinated Pollutants [PDF]
Jennifer G. Becker +2 more
openalex +1 more source
Reductive Transformations of Anthropogenic Chemicals in Natural and Technical Systems
Reductive transformation reactions of chemical pollutants (e.g., polyhalogenated hydrocarbons, aromatic azo and nitro compounds, chromium(VI) species) in the environment are important both from an ecotoxicological and from an environmental ...
René P. Schwarzenbach +4 more
doaj
Effect of temperature on microbial reductive dehalogenation of chlorinated ethenes: a review [PDF]
Mohammad Sufian Bin Hudari +3 more
openalex +1 more source
Isolation from Estuarine Sediments of a Desulfovibrio Strain Which Can Grow on Lactate Coupled to the Reductive Dehalogenation of 2,4,6-Tribromophenol [PDF]
Alfred W. Boyle +2 more
openalex +1 more source
Selective dechlorination of organic chlorides over hydrogen evolution reaction (HER) remains a challenge because of their coincidence. Nanoscale zerovalent iron (nFe0) draws a promising picture of in situ groundwater dechlorination, but its ...
Xiaohong Hu +10 more
doaj +1 more source

