Design of highly efficient organic photocatalysts for visible-light driven reductive dehalogenation of aryl halides [PDF]
Department of Materials Science and EngineeringAbstracting halide ions from organohalide compounds and generating free-radical to produce reactive intermediate have proven to be very important and useful step in chemical synthesis and have also found ...
Kim, Doyon
core
Dehalogenation of polychlorinated biphenyls and polybrominated diphenyl ethers using a hybrid bioinorganic catalyst [PDF]
The environmentally prevalent polybrominated diphenyl ether (PBDE) #47 and polychlorinated biphenyls (PCBs) #28 and #118 were challenged for 24 hours with a novel biomass-supported Pd catalyst (BioPd0).
Alcock +24 more
core +2 more sources
π‐Expanded Fluoranthenes as Chromophores With Tailored Properties
A series of π‐expanded fluoranthene scaffolds selectively functionalized with electron donors and acceptors were synthesized. The evolution of the structural, optoelectronic, and redox properties in relation to substitution and cyclization was comprehensively studied both in experiment and in theory. The results identify the compounds as highly tunable
Silas C. Eiden +4 more
wiley +1 more source
Cofactor Selectivity in Methylmalonyl Coenzyme A Mutase, a Model Cobamide-Dependent Enzyme. [PDF]
Cobamides, a uniquely diverse family of enzyme cofactors related to vitamin B12, are produced exclusively by bacteria and archaea but used in all domains of life.
Mok, Kenny +5 more
core +1 more source
Advances in conjugated porous polymers via high internal phase emulsion templating
This mini‐review highlights the design, synthesis and potential applications of π‐conjugated polyHIPEs, emphasizing their unique hierarchical structure and tunable properties. The work outlines innovative synthetic strategies and explores their promising roles in photocatalysis and environmental remediation, paving the way for future advancements in ...
Julie‐Lisa Malaval +4 more
wiley +1 more source
Impacts of Co-Solvent Flushing on Microbial Populations Capable of Degrading Trichloroethylene [PDF]
With increased application of co-solvent flushing technologies for removal of nonaqueous phase liquids from groundwater aquifers, concern over the effects of the solvent on native microorganisms and their ability to degrade residual contaminant has also ...
Alvarez-Cohen L +15 more
core +2 more sources
Strain‐Activated Photo‐Dehalogenation Unlocks Low‐Energy One and Two‐Photon 3D Microfabrication
5,14‐NMI‐Cz acts, conversely to its 7,10‐NMI‐Cz(7,10‐'dibromo‐2‐(2,6‐diisopropylphenyl)‐1H‐benzo[lmn]carbazolo[9,1‐bc][2,8]phenanthroline‐1,3(2H)‐dione) counterpart, as modular photoinitiator with panchromatic photoactivity, featuring a weak C–Br bond from geometric strain for efficient Type I & II initiation. These studies demonstrate applicability of
Kacper Piskorz +10 more
wiley +1 more source
Reductive dechlorination in the energy metabolism of anaerobic bacteria [PDF]
Within the last few decades, several anaerobic bacteria have been isolated which are able to reductively dechlorinate chlorinated aliphatic and aromatic compounds at catabolic rates.
Diekert, Gabriele +2 more
core
The Antarctic Dietzia and Pusillimonas isolates were tested for bioremediation applications. Genomic analyses revealed the potential to degrade complex organic compounds, potential virulence factors and resistance genes. Physiological assays showed a wide range of adaptation to abiotic factors and sensitivity to different groups of antibiotics ...
Tomasz Krucoń +4 more
wiley +1 more source
Background Mangrove sediment microbes are increasingly attracting scientific attention due to their demonstrated capacity for diverse bioremediation activities, encompassing a wide range of environmental contaminants.
Sultan M. Alsharif +3 more
doaj +1 more source

