Results 51 to 60 of about 2,154 (122)

Z‐Scheme BiOCl‐Based Photocatalysts: Recent Advances in Designing, Structural Engineering, Formation Mechanisms, and High Performance Photocatalytic Environmental Remediation

open access: yesEcoEnergy, EarlyView.
This review deals with the recent advancements in design and engineering of BiOCl‐based Z‐scheme photocatalysts with emphasis on tailoring of structural, optoelectronic properties and heterojunction assembly for environmental applications including photodegradation of industrial organic waste, pharmaceuticals, pesticides, herbicides, toxic heavy metals,
Sakshi Sharma   +7 more
wiley   +1 more source

Advances in conjugated porous polymers via high internal phase emulsion templating

open access: yesPolymer International, EarlyView.
This mini‐review highlights the design, synthesis and potential applications of π‐conjugated polyHIPEs, emphasizing their unique hierarchical structure and tunable properties. The work outlines innovative synthetic strategies and explores their promising roles in photocatalysis and environmental remediation, paving the way for future advancements in ...
Julie‐Lisa Malaval   +4 more
wiley   +1 more source

Bacterial diversity and reductive dehalogenase redundancy in a 1,2-dichloroethane-degrading bacterial consortium enriched from a contaminated aquifer

open access: yesMicrobial Cell Factories, 2010
Background Bacteria possess a reservoir of metabolic functionalities ready to be exploited for multiple purposes. The use of microorganisms to clean up xenobiotics from polluted ecosystems (e.g.
Wittebolle Lieven   +7 more
doaj   +1 more source

Abundance of atrazine degrading genes trzN versus atzA in soil cultures and in situ degradation rates

open access: yesPest Management Science, EarlyView.
Atrazine degradation in agricultural soils showed in situ half‐lives of 36–225 days. Field and laboratory results indicate active microbial hydrolysis driven mainly by trzN. Biphasic degradation sustains long‐term persistence, maintaining the potential for groundwater contamination despite reduced immediate leaching risk.
Truphena Akinyi   +3 more
wiley   +1 more source

Effects of humic electron mediators on reductive dechlorination of polychlorinated biphenyl by consortia enriched from terrestrial and marine environments

open access: yesFrontiers in Microbiology
Humic electron mediators can facilitate the reductive dehalogenation of organohalogenated compounds by accelerating electron transfer. To investigate the effect of humic electron mediators on the microbial anaerobic reductive dechlorination of ...
Qiong Wang   +12 more
doaj   +1 more source

Visible‐light‐promoted catalyst‐free benzylic C‐H oxidation using molecular oxygen as a green oxidant

open access: yesSmart Molecules, EarlyView.
A green and simple photo‐oxygenation of benzylic C‐H bond with molecular oxygen was developed for the preparation of a series of carbonyl compounds. The straightforward C‐H carbonylation strategy features catalyst‐ and additive‐free reaction conditions, only oxygen as a green oxidant, broad scope and scalable, and the simple‐operation nature.
Jianing Li   +6 more
wiley   +1 more source

Activation of Aryl Halides by Triplet–Triplet Annihilation Upconversion Enabling Coupling Processes Under an Open‐to‐Air Environment

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 24, 23 June 2026.
Triplet–triplet annihilation upconversion (TTA‐UC) performed inside supramolecular viscoelastic gels enables efficient CC and C–heteroatom coupling reactions under green LED irradiation in open‐air conditions. The gel network restricts oxygen diffusion, preserves triplet states, and allows aryl halide activation through upconverted excited states ...
Daniel Álvarez‐Gutiérrez   +4 more
wiley   +1 more source

Expedient Discovery of a Metallaphotoredox Cyanomethylation for Synthesizing α‐Aryl Nitriles

open access: yesChemistry – A European Journal, Volume 32, Issue 23, 16 June 2026.
A metallaphotoredox cyanomethylation reaction has been developed for the synthesis of valuable α‐aryl nitrile intermediates. The methodology was successfully applied to diverse medicinally‐relevant substrates, providing an expedient route to anti‐cancer Senexin compounds, while also removing the need for toxic cyanide reagents. The mechanism was probed
Gemma C. Cook   +6 more
wiley   +1 more source

Genome sequence of Desulfitobacterium hafniense DCB-2, a Gram-positive anaerobe capable of dehalogenation and metal reduction

open access: yesBMC Microbiology, 2012
Background The genome of the Gram-positive, metal-reducing, dehalorespiring Desulfitobacterium hafniense DCB-2 was sequenced in order to gain insights into its metabolic capacities, adaptive physiology, and regulatory machineries, and to compare with ...
Kim Sang-Hoon   +6 more
doaj   +1 more source

Heterogeneous Iodine Chemistry Impacts Reactive Halogen and Oxidant Abundances

open access: yesGeophysical Research Letters, Volume 53, Issue 11, 16 June 2026.
Abstract Tropospheric reactive halogens influence the oxidizing capacity of the atmosphere. Although previous studies have shown that iodine exerts the strongest impact on tropospheric ozone concentrations compared to chlorine and bromine, the impact of aerosol iodide recycling back to the gas phase on oxidants has not been estimated prior to this work.
Allison R. Moon   +22 more
wiley   +1 more source

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