Results 71 to 80 of about 2,211 (175)
Halogen Bonding‐Mediated Radical Cyclisation of Aryl Halides
Halogen bonding between aryl halides and tertiary amines facilitates photochemically initiated radical cyclisations that proceed at high concentration, greatly improving sustainability. Aryl halides are convenient, stable precursors to synthetically versatile aryl radicals, but the generation of the latter typically requires either stoichiometric tin ...
Emma L. Jones +5 more
wiley +1 more source
Substrate Electronics Dominate the Rate of Reductive Dehalogenation Promoted by the Flavin-Dependent Iodotyrosine Deiodinase. [PDF]
Kozyryev A, Lemen D, Dunn J, Rokita SE.
europepmc +1 more source
Dual C-Br Isotope Fractionation Indicates Distinct Reductive Dehalogenation Mechanisms of 1,2-Dibromoethane in Dehalococcoides- and Dehalogenimonas-Containing Cultures. [PDF]
Palau J +9 more
europepmc +1 more source
Redox Modulation in Truxene‐Based Phosphaalkenes Through Peripheral Substitution
Peripheral halogenation, followed by the sequential incorporation of one, two, and three phosphaalkene acceptor units, induces progressive distortion of the truxene framework, modulates the frontier molecular orbital energies, and systematically shifts the reduction potentials to milder values.
Toma Bhowmick +3 more
wiley +1 more source
Sol-Gel Heterogeneization of an Ir(III) Complex for Sustainable Visible-Light Redox Photocatalysis
Photocatalysis is a key strategy for the development of sustainable solar-driven chemical processes. In this work, we report the synthesis and characterization of a novel organometallo–ionosilica material derived from the self-condensation of an ...
Janira Herce +4 more
doaj +1 more source
Dry‐season pollutant concentration drives microbial restructuring in Bangladesh's Shitalakshya River, shifting communities from Myroides to stress‐tolerant genera while enriching metal resistance genes and efflux pumps, revealing non‐antibiotic co‐selection as a key driver of antimicrobial resistance in urban waters.
Muhammad Ehteshamul Haque +3 more
wiley +1 more source
Actions for improving water quality are critical and include the remediation of polluted groundwater. The effectiveness of the remediation strategy to remove contamination by chlorinated solvents may be increased by combining physicochemical treatments ...
Laura Lorini +5 more
doaj +1 more source
Porous Organic Polymers: From Molecular Design to Scalable Technologies
This review introduces porous organic polymers (POPs) for a wide range of applications, including energy storage, gas adsorption, catalysts, adsorbents, biomedical applications, sensors, and other exciting fields, and critically analyzes the synthesis and modification, and how structural topology influences the composites' architecture of POPs, along ...
Hossein Mashhadimoslem +12 more
wiley +1 more source
Following the discovery of oxadiazin‐5‐ones as partial inhibitors of the ATP synthase, we herein report the synthesis of a library of pyrazolidine‐3‐ones and pyrazol‐3‐ones, designed by reducing the six‐membered N–N heterocycles to five‐membered rings.
Lisa Reichert +8 more
wiley +1 more source
Versatile Palladium‐Catalyzed C‐H Arylation of Fluoroarenes with 2‐Chloropyridine Derivatives
Direct C─H arylation of fluoroarenes with 2‐chloropyridines is enabled by a simple Pd/SPhos system in isopropyl acetate. The method uses inexpensive reactants and shows broad scope and high yields. DFT computations explain reactivity and selectivity.
Federico Belnome +6 more
wiley +1 more source

