Fe(III)/Pyridine N-oxide LMCT Photocatalysis for Unactivated C(sp<sup>3</sup>)-H Functionalizations. [PDF]
ACS CatalLuo J +5 more
europepmc +1 more source
Stereoselective Construction of Benzo‐Fused Tetrahydropyrrole Thiazines From Saccharin
European Journal of Organic Chemistry, EarlyView.Saccharin was used as a template to construct a series of 10a‐substituted, benzo‐fused, pyrrolo thiazinone dioxides. Thereafter, diastereo‐divergent 10‐keto reduction gave either diastereomeric alcohol in a process that did not rely on the substituent at 10a's identity.
Seanán Doyle +8 more
wiley +1 more source
Synthesis of a series of vicinal diamines with potential biological activity
Open Chemistry, 2004 Kurteva Vanya, Lyapova Maria
doaj +1 more source
HMPA-Enabled Direct γ'-Arylation of Cyclic Vinylogous Esters. [PDF]
Org LettLi YX, Zhao WT, Wu YK.
europepmc +1 more source
Diastereoselective Synthesis of Highly Substituted Methylene Cyclobutanes by Pd Catalysis
European Journal of Organic Chemistry, EarlyView.A chemo‐ and diastereoselective palladium‐catalyzed intramolecular coupling/cyclization of borylated 1,5‐dienes, readily accessible by allene allylboration, with iodoarenes enables the synthesis of highly substituted methylene cyclobutanes. The method exhibits broad scope, high functional group tolerance, and complete enantiospecificity.
Jose M. Malga +1 more
wiley +1 more source
Unveiling the reaction mechanism and the regioselectivity of Diels-Alder cycloadditions between 2-methoxy-3-thiophenylbutadiene and methyl vinyl ketone using topological tools. [PDF]
RSC AdvChellegui M +4 more
europepmc +1 more source
Retro‐Hetero‐Michael Addition Strategies in Organic Synthesis
European Journal of Organic Chemistry, EarlyView.In this review, synthetic approaches to carbo‐ and heterocyclic compounds, including natural products, published in the last 15 years (2011–2025) which have either relied upon or included a retro‐hetero‐Michael addition step at any stage are discussed.
Dina Scarpi, Ernesto G. Occhiato
wiley +1 more source
Recent advances in copper-catalyzed direct hydroamination of alkenes with (hetero)aromatic amines. [PDF]
Beilstein J Org ChemLee H, Lee Y.
europepmc +1 more source
Mechanistic Dichotomy in Enantioselective Pd‐Catalyzed Alkylation of Pyrroles With Diazoesters
European Journal of Organic Chemistry, EarlyView.Ligand‐controlled mechanistic divergence controls the Pd‐catalyzed asymmetric alkylation of pyrroles with diazoesters. While bipyridine ligands promote a conventional metal‐carbene pathway, bipyridine‐N,N′‐dioxide ligands redirect catalysis through electrophilic CH metalation before carbene transfer.
Vladimir Yu. Vaganov +5 more
wiley +1 more source
Experimental and DFT studies on the regioselective methanolysis of 5-azido-9-oxabicyclo[6.1.0]nonan-4-yl 4-nitrobenzoate isomers. [PDF]
Beilstein J Org ChemPolat İ, Eşsiz S, Salamci E.
europepmc +1 more source