2-Aminooxazoles and 2-aminothiazoles: green regioselective synthesis and bioactivity. [PDF]
Yenare PP, Patare RD, Sanap KK.
europepmc +1 more source
Photocatalysis‐Triggered Click Reactions and Applications
Photoclick chemistry offers broad applications ranging from materials science to bioconjugation, with precise spatiotemporal control over click reactions. Initially limited to UV activation, recent advances have extended photoclick processes to the visible and NIR regions thanks to the photocatalysis.
Margaux Walter +2 more
wiley +1 more source
Traversing the Regioselectivity of Intermolecular Pericyclic Aryne Reactions: Total Syntheses of Laetevirenol A and Isoampelopsin D. [PDF]
Nguyen LH +9 more
europepmc +1 more source
Bromonitroalkanes in Organic Synthesis
α,α‐Bromonitroalkanes (BNAs) exhibit chameleon‐like reactivity, serving as carbene, radical, carbanion, and carbocation synthons. This mini‐review summarizes the different reaction modes and highlights recent developments in thermal and photochemical processes. α,α‐Bromonitroalkanes (BNAs) exhibit chameleon‐like reactivity, serving as carbene, radical,
Magdalena Koch, Oliver Reiser
wiley +1 more source
Regioselective and Stereodivergent C-H Functionalization of Internal Alkenes. [PDF]
Ryutov EA +5 more
europepmc +1 more source
Palladium(II)‐catalyzed intramolecular C─H alkenylation of cinnamides allows the atroposelective synthesis of axially chiral 4‐arylquinolones, with the chirality being installed by ring formation. DFT studies have shown that the reaction proceeds by prior activation of the alkene and the enantioselectivity is determined during the β‐hydride elimination
Brenda Fundora +8 more
wiley +1 more source
Mo‐Catalyzed Synthesis of 3‐Substituted Quinolines From Nitroarenes and Aldehydes
A one‐pot Friedländer synthesis of 3‐substituted quinolines from readily available o‐nitrobenzaldehydes and aldehydes or acetals has been developed under dioxomolybdenum(VI) catalysis. Pinacol acts as a benign reductant, enabling in situ nitroarene reduction and annulation without isolation of o‐aminobenzaldehydes and provides access to diverse ...
Raúl Martínez‐González +3 more
wiley +1 more source
Chiral Copper(II) Complex‐Catalyzes Site‐Selective Monofunctionalization of Levoglucosan Analogs
A chiral copper‐catalyzed strategy for the site‐selective functionalization of levoglucosan and its analogs is reported. Using CuCl2 in combination with a chiral bis(oxazoline) ligand, selective functionalization of the O2 or O4 hydroxyl group was achieved, with the regioselectivity controlled by the ligand configuration.
Christina Leclerc +6 more
wiley +1 more source
Divergent ring opening and functionalization of N-alkyl aziridines via boryl radical fragmentation. [PDF]
Peng P +5 more
europepmc +1 more source
Carbon‐Supported Catalytic Systems Assembled by π–π Interactions
This review explores the noncovalent immobilization of organic and organometallic catalysts on carbonaceous supports through π–π interactions, highlighting its potential to enhance catalyst recovery, recyclability, and the sustainability of organic synthesis.
Chloé Jamalkhan +8 more
wiley +1 more source

