Results 161 to 170 of about 15,429 (247)

Stereoselective and Diastereospecific Aminosilylation and Hydrosilylation of Heterobicyclic Alkenes by Copper Catalysis Under Mild Conditions

European Journal of Organic Chemistry, EarlyView.
An efficient and straightforward methodology for the stereoselective and diastereospecific aminosilylation and hydrosilylation of heterobicyclic norbornene derivatives is introduced. The mild conditions enable the functionalization of norbornene substrates with broad functional‐group tolerance.
Daniel Kamzol, Wende Chen, Aleksander Hoffman, René Wilhelm   +3 more
wiley   +1 more source

NiH-Catalyzed Enantioconvergent α-Alkenylation of Carbonyl Compounds via Markovnikov Alkyne Hydronickellation. [PDF]

Angew Chem Int Ed Engl
Nam H, Jang S, Kim D, Seo S.
europepmc   +1 more source

Endohedral fullerenes as qubits: From synthesis to quantum computing applications

InfoMat, EarlyView.
Endohedral fullerenes emerge as promising platforms for qubits and qudits. This review surveys the primary synthesis routes, from arc‐discharge to high‐yield molecular surgery. It then details spin manipulation and readout in key systems, including metal‐based, cluster, and nitrogen‐containing fullerenes.
Jeong‐Seok Nam, Jiye Han, Jin‐Myung Choi, Franklin H. Cho, Daniel K. Park, Seunghee Park, Yoshifumi Hashikawa, Yasujiro Murata, Eunsang Kwon, Dong‐Hwan Kim, Junki Kim, Il Jeon   +11 more
wiley   +1 more source

Determinants of undesired α2-6-sialoside formation by PmST1 M144D. [PDF]

Org Biomol Chem
Mozaneh F, Joe M, Wakarchuk WW, Wu P, Macauley MS.   +4 more
europepmc   +1 more source

AI‐Driven Synthesis in Medicinal Chemistry: Integrating Large Language Models, Robotic Automation, and Sustainability Metrics to Accelerate Drug Discovery

Medicinal Research Reviews, EarlyView.
ABSTRACT Artificial intelligence (AI) is transforming synthetic chemistry from task‐specific predictors into integrated platforms that unify retrosynthesis, reaction optimization, and closed‐loop robotic automation. This review highlights how AI‐assisted planning and robotic execution shorten cycle times, reduce step counts, and improve route ...
Amit Gangwal, Antonio Lavecchia
wiley   +1 more source

A Revisit of Co(PMe₃)₄‑Catalyzed Hydrophosphination of Phenylacetylene with HPPh₂. [PDF]

Organometallics
Jayawardhena JPID, Krause JA, Guan H.
europepmc   +1 more source

Main‐chain polyfullerenes: Taking fullerene to the next dimension

Polymer International, EarlyView.
This short review appraises main‐chain polyfullerenes. Their slow development over 30 years has suddenly boomed with a rapid growth due to exciting developments in solar energy. Abstract This mini‐review gives an overview of the development, chemistry, properties and applications of main‐chain polyfullerenes.
Marco Antônio GB Gomes, Orisson Ponce Gomes, Patricia Targon Campana, Didier Bégué, Roger C Hiorns   +4 more
wiley   +1 more source

Chiral poly(aza-norbornene) derivatives with tunable tacticity and living ROMP capability. [PDF]

Chem Sci
Bai J, Wang Y, Wang Y, Zhang N, Wang X, Xu Y, You W.   +6 more
europepmc   +1 more source

Surface Engineering of Ti3C2Tx MXenes via Silanol Functionalization for Improved Electrochemical Performance

Small, EarlyView.
This study explores the covalent functionalization of Ti3C2Tx using 5,5′‐bis(triisopropoxysilyl)‐2,2′‐bipyridine in different solvents, revealing that only m‐xylene enables effective covalent bonding, ensuring structural stability and preventing layer swelling.
Abelardo Sánchez‐Oliva, Verónica Montes‐García, Ke Li, Kaitlyn Prenger, Xuyun Guo, Iwona Janica, Wojciech Kukułka, Adrián Tamayo, Pilar Prieto, Paolo Samorì, Valeria Nicolosi, Artur Ciesielski   +11 more
wiley   +1 more source

P450 engineering via structure-guided rational design achieves high C21-selectivity and bioconversion in steroid biosynthesis. [PDF]

Synth Syst Biotechnol
Yang J, Li R, Gao Q, Ma L, Wang Q, Ma G, Fan Y, Li S, Xu LH.   +8 more
europepmc   +1 more source