Results 171 to 180 of about 37,566 (244)

Highly Tunable Thermal Properties of Multifunctional Thiol‐Ene Networks Derived From Sugar‐Based Monomers

Journal of Polymer Science, EarlyView.
Eleven allylated sugar frameworks combined with seven dithiol compounds create 77 thiol‐ene networks with a wide range of thermomechanical properties. Analysis based on composition reveals that both the sugar's functionality and the scaffold's structure work in conjunction with dithiol chemistry to influence the rubbery modulus, glass‐transition ...
Gether B. Coloma, Mudassir M. Syed, Tyler S. Kristufek, Lukas Whitehead, Eden Sahra Girma, Itzel Campuzano‐Yeverino, Samantha L. Kristufek   +6 more
wiley   +1 more source

Design and synthesis of responsive glycopolymers for biomedical and environmental applications

Responsive Materials, EarlyView.
This review highlighted recent advances in the synthetic methodology of polymerization and post‐polymerization modification, which enable precise structural control and broaden the applications of responsive glycopolymers in biomedical and environmental fields. Abstract Glycopolymers are a unique class of synthetic polymers bearing pendant carbohydrate
Arpita Samal, Shubhi Dwivedi, Mahesh Peddigari, Abhijit Sau   +3 more
wiley   +1 more source

An autonomous lab for data-driven homogeneous catalysis. [PDF]

Nat Commun
Bennett JA, Orouji N, Velayati A, Reynolds EF, Porowski ME, Saha M, Billodeaux D, Miller AJM, Abolhasani M.   +8 more
europepmc   +1 more source

Surface Engineering of Ti3C2Tx MXenes via Silanol Functionalization for Improved Electrochemical Performance

Small, EarlyView.
This study explores the covalent functionalization of Ti3C2Tx using 5,5′‐bis(triisopropoxysilyl)‐2,2′‐bipyridine in different solvents, revealing that only m‐xylene enables effective covalent bonding, ensuring structural stability and preventing layer swelling.
Abelardo Sánchez‐Oliva, Verónica Montes‐García, Ke Li, Kaitlyn Prenger, Xuyun Guo, Iwona Janica, Wojciech Kukułka, Adrián Tamayo, Pilar Prieto, Paolo Samorì, Valeria Nicolosi, Artur Ciesielski   +11 more
wiley   +1 more source

Cobalt-Catalyzed Cyclohydrocarbonylations: Syntheses of Saturated Heterocycles Promoted by Light. [PDF]

J Am Chem Soc
Rodriguez MR, Jung M, Faculak MS, Handlin AD, Liu S, Alexanian EJ.   +5 more
europepmc   +1 more source

Regioselective C‐H Oxyfunctionalization of Aliphatic Acids Through a Consecutive Biosolar Cascade

Small, EarlyView.
Photobiocatalytic regioselective oxyfunctionalization of aliphatic acids is realized by combining a dual‐alkali‐metal‐doped carbon nitride photocatalyst (NaK‐ACN) with CYP152A1 peroxygenase. The synergistic effect of co‐dopants modulates electron distribution and the surface electric field, enhancing 2e− ORR activity.
Chung Hyun Lee, Min Seok Byun, Hyun‐Woo Kim, Kunwoo Park, Donghun Kim, Seungbum Hong, Soo‐Jin Yeom, Chan Beum Park   +7 more
wiley   +1 more source

Endocytosis‐independent cytosolic entry of messenger RNA via fluorous bilayer zippering attenuating Toll‐like receptor signaling and enables ischemic tissue salvage

Smart Molecules, EarlyView.
The present study establishes a paradigm shift in synthetic mRNA delivery through the convergence of three orthogonal chemistries—perfluoro‐acylation, bio‐orthogonal click cross‐linking, and disulfide reduction—within a single, modular polymer architecture. Abstract A fundamental constraint of conventional messenger RNA (mRNA) delivery systems is their
Yue Wang, Haitao Xie, Guoqing Xiang, Yanhua Li, Changgui Tong, Hongyan Cui, Qixian Chen, Haidong Li, Yan Zhao   +8 more
wiley   +1 more source

Catalyst-controlled regiodivergence in enantioselective synthesis of spirocyclic γ- versus δ-lactams. [PDF]

Nat Commun
Wu SH, Gong F, Bi YB, Bai YZ, Zhong C, Cao Z, Deng QH.   +6 more
europepmc   +1 more source

Harnessing the nonthermal effects of ultrasound for cancer treatment: From mechanisms to applications

Smart Molecules, EarlyView.
Nonthermal ultrasound transforms acoustic energy into diverse therapeutic bioeffects through cavitation, mechanical stimulation, and physicochemical activation. This review discusses how acoustic parameters, biological mechanisms, and responsive materials interact to influence nonthermal ultrasound‐enabled cancer therapies. Mechanism‐guided engineering
Liu Wang, Huan Tang, Yue Pan, Mingle Li, Weijie Zhao, Kai Liu   +5 more
wiley   +1 more source

Reactivity of Nitroarenes toward Alkyl Radicals Enables Direct C-H Alkylation. [PDF]

J Am Chem Soc
Das K, Chakraborty S, Paenurk E, König B.   +3 more
europepmc   +1 more source