Mechanistic Insights into the Regioselective (3 + 2) Cycloaddition of Unsymmetrical Cyclopropenones with Elemental Sulfur: Experimental and Computational Studies. [PDF]
Rivero P +8 more
europepmc +1 more source
Regioselectivity Study of Contrasteric Aromatic Claisen Rearrangements and Their Utilization in the Total Syntheses of 5-Hydroxymellein and Botyroisocoumarin A. [PDF]
Tanas DK +14 more
europepmc +1 more source
Mechanochemical ligand-controlled regiodivergent hydroarylation of alkenes via iron-catalyzed C-H activation. [PDF]
Zhang ZJ, Liu Z, Chen X, Ackermann L.
europepmc +1 more source
Modular and diverse synthesis of oxaheterocycles <i>via</i> Pd-catalyzed migratory 1,<i>n</i>-cycloannulation of alkenes. [PDF]
Wang JP, Wu Y, Wang P.
europepmc +1 more source
Enantioselective synthesis of configurationally stable [5]helicenes containing 1,2-azaborine units. [PDF]
Olguin C +10 more
europepmc +1 more source
openaire
Related searches:
Regioselective Semihydrogenation of Dienes
The Journal of Organic Chemistry, 2011A one-pot, three-step strategy for the regioselective semihydrogenation of dienes is described. This procedure uses 9-BBN-H as a temporary protective group for alkenes. Yields range from 55% to 95%, and the reaction is tolerant of a variety of common functional groups.
Thomas J A, Graham +3 more
openaire +2 more sources
Regioselective Allylzincation of Alkenylboronate
Organic Letters, 2001[reaction: see text] Boryl substitution on an olefin activates the olefinic double bond toward addition of an organozinc reagent. Addition of an allylic zinc reagent to an alkenylboronate thus takes place smoothly to afford a variety of gem-zincio/boryl species.
M, Nakamura +3 more
openaire +2 more sources
Regioselectivity in the Nitration of Dialkoxybenzenes
The Journal of Organic Chemistry, 2011Dinitrodialkoxybenzene derivatives are important precursors for Schiff base macrocycles and a variety of other molecules. During our investigations, we have found that the dinitration reaction of 1,2-dialkoxybenzenes proceeds with unusual regioselectivity, giving exclusively the desired 1,2-dialkoxy-4,5-dinitrobenzene product, but we have been unable ...
Kevin, Shopsowitz +2 more
openaire +2 more sources
Regioselective Synthesis of Benzofuranones and Benzofurans
The Journal of Organic Chemistry, 2021Reaction of 3-hydroxy-2-pyrones with nitroalkenes bearing ester groups gives benzofuranones. The reaction allows regioselective preparation of the benzofuranones with programmable substitution at any position. Complex substitution patterns are readily created. The substituted benzofuranones can be converted to substituted benzofurans.
Xiaojie Zhang, Christopher M. Beaudry
openaire +2 more sources

