Results 61 to 70 of about 2,189,828 (267)

Facile Synthesis of the Naturally Cytotoxic Triterpenoid Saponin Patrinia-Glycoside B-II and Its Conformer

open access: yesMolecules, 2013
The first chemical synthesis of the natural triterpenoid saponin Patrinia-glycoside B-II, namely oleanolic acid 3-O-α-L-rhamnopyranosyl-(1→2)-[β-D-gluco-pyranosyl-(1→3)]-α-L-arabinopyranoside, has been accomplished in a linear 11-step sequence 11 with 9.
Li Ren   +6 more
doaj   +1 more source

A Cation-π Interaction Discriminates among Sodium Channels That Are Either Sensitive or Resistant to Tetrodotoxin Block [PDF]

open access: yes, 2007
Voltage-gated sodium channels control the upstroke of the action potential in excitable cells of nerve and muscle tissue, making them ideal targets for exogenous toxins that aim to squelch electrical excitability.
Ahern, Christopher A.   +4 more
core   +2 more sources

Persistence of benthiocarb in soil: influence of ultraviolet and sunlight

open access: yesOrbital: The Electronic Journal of Chemistry, 2008
Persistence of benthiocarb in soil as affected by UV and sunlight exposure was studied. Treated soil was placed in petri plate, brought to field capacity moisture and then exposed to UV and sunlight.
Md. Wasim Aktar   +2 more
doaj  

N,N-bis-(dimethylfluorosilylmethyl)amides of N-organosulfonylproline and sarcosine: synthesis, structure, stereodynamic behaviour and in silico studies [PDF]

open access: yes, 2016
(O→Si)-Chelate difluorides R3R2NCH(R1)C(O)N(CH2SiMe2F)2 (9a–c, R1R2 = (CH2)3, R3 = Ms (a), Ts (b); R1 = H, R2 = Me, R3 = Ms (c)), containing one penta- and one tetracoordinate silicon atoms were synthesized by silylmethylation of amides R3R2NCH(R1)C(O ...
Arkhipov, Dmitry E.   +10 more
core   +1 more source

Degradation dynamics and risk assessment of chlorpyriphos in/on cabbage under different culinary processes

open access: yesOrbital: The Electronic Journal of Chemistry, 2008
Chlorpyriphos 20 EC was applied at the rate of 500 g a.i. ha-1 in Cabbage heads and the samples harvested at intervals of 0 (2 hours after application), 1 and 7 days after application.
Md. Wasim Aktar   +3 more
doaj  

Polymers Interfacing with Biology

open access: yesCHIMIA, 2011
The development of various controlled radical polymerization techniques as well as site- and residue specific strategies to modify peptides/proteins with synthetic polymers have made polymer chemistry a powerful tool to address materials ...
Frederik Wurm, Harm-Anton Klok
doaj   +1 more source

The role of tyrosine in protein-dopamine based bioinspired adhesives: the stoichiometry that maximizes bonding strength

open access: yesFrontiers in Biomaterials Science, 2023
Nature has evolved adhesive materials adaptive for several different environments by using versatile chemistry that largely relies on two simple components: catechols and polypeptides.
Marco Lo Presti   +9 more
doaj   +1 more source

Iron-mediated Preparation of Vinylcyclopropanes. Scope, Mechanism, and Applications [PDF]

open access: yes, 2003
The addition of stabilized carbon nucleophiles to tricarbonyl(1-methoxycarbonylpentadienyl)iron(1+) cation (1a) proceeds via attack at C2 on the face of the ligand opposite the Fe(CO)3 group to generate tricarbonyl(pentenediyl)iron complexes 2. Oxidation
Cao, Yeyu   +3 more
core   +1 more source

Uncovering the Mechanism of Aggregation of Human Transthyretin. [PDF]

open access: yes, 2015
The tetrameric thyroxine transport protein transthyretin (TTR) forms amyloid fibrils upon dissociation and monomer unfolding. The aggregation of transthyretin has been reported as the cause of the life-threatening transthyretin amyloidosis.
Cascio, Duilio   +9 more
core   +2 more sources

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