Rhodium-catalyzed enantioselective intermolecular C-H silylation of simple arenes: synergistic substituent effects overcome silane redistribution to enable synthesis of Si-stereogenic arylsilanes. [PDF]
Liu L +9 more
europepmc +1 more source
A one‐step, asymmetric reductive coupling of alkynes and oxa‐ and aza‐bicyclic olefins using a cobalt/photoredox catalytic system through desymmetrization. ABSTRACT Bicyclo[2.2.1]heptane frameworks represent a privileged structural motif prevalent in numerous natural products and bioactive molecules.
Subhankar Pradhan +5 more
wiley +1 more source
Reassessment of Recycling Rates of Platinum Group Metals (PGMs) and Their Impact on Sustainability Models. [PDF]
Ryan M +7 more
europepmc +1 more source
Regulation of molecular packing, phototoxicity, and ROS output of AIE photosensitizers is achieved through carboxylation and alkyl‐chain‐length tuning. The probe designed via this strategy enables super‐resolution visualization of inner‐mitochondrial‐membrane cristae dynamics under controlled oxidative stress, and fluorescence‐lifetime imaging of ...
Kongqi Chen +5 more
wiley +1 more source
Di-Silyl Rhodium(III) and Iridium(III) Complexes as Catalysts in Carbene Insertion Reactions into Hydrosilanes. [PDF]
Azpiazu-Galarza A +4 more
europepmc +1 more source
Generation of Probabilistic Bits by Exploiting Orthogonal Spin Currents in Magnetic Trilayers
Fe/Ti/CoFeB trilayers generate orthogonal spin currents that drive stochastic spin–orbit‐torque switching for probabilistic‐bit operation. The switching probability is continuously controlled by the in‐plane magnetic field and drive current, enabling tunable random bit generation.
Donghyeon Han +17 more
wiley +1 more source
Triflate-Enabled Rhodium-Catalyzed Cross-Dehydrogenative Si-N Bond Formation from Hydrosiloxanes. [PDF]
Padilla M +4 more
europepmc +1 more source
ABSTRACT Methane's efficient catalytic removal is vital for sustainable development. Bimetallic catalysts, though promising for methane activation, pose a design challenge due to their complex compositional space. This work introduces an integrated framework that combines high‐throughput density functional theory (DFT) and interpretable machine ...
Mingzhang Pan +8 more
wiley +1 more source
Atomic-Scale Understanding of Doping Effects in BaTiO<sub>3</sub> in the Presence of Water: Implications for Photocatalytic Water Splitting. [PDF]
Zakiyeva ZY +10 more
europepmc +1 more source

