Rhodium-Catalyzed C-H Activation/Annulation of <i>N</i>‑Chlorobenzamide Derivatives with Alkynes. [PDF]
Jiang QX +10 more
europepmc +1 more source
A novel high‐entropy perovskite oxide, (Gd0.2Tb0.2Dy0.2Ho0.2Er0.2)FeO3, was successfully synthesized for advanced hydrogen sulfide gas detection. By synergistically coupling high‐entropy‐induced local lattice distortion with weak magnetic field modulation, the tailored material generates abundant active sites. This innovative dual strategy dramatically
Yunfei Wang +7 more
wiley +1 more source
Reassessment of Recycling Rates of Platinum Group Metals (PGMs) and Their Impact on Sustainability Models. [PDF]
Ryan M +7 more
europepmc +1 more source
A nickel‐catalyzed three‐component reductive fluoroalkylation‐amination strategy of N‐vinylamides for the direct access to the α‐amidyl‐β‐difluoroalkyl amines was reported here. The synthetic method features with broad substrate scope, mild conditions, high functional group tolerance, and convenience to handle.
Chang Xu +8 more
wiley +1 more source
Rhodium-catalyzed enantioselective intermolecular C-H silylation of simple arenes: synergistic substituent effects overcome silane redistribution to enable synthesis of Si-stereogenic arylsilanes. [PDF]
Liu L +9 more
europepmc +1 more source
Polymer‐Grafted Cu(II) Metal–Organic Polyhedra as Scalable, Melt‐Processable Porous Materials
The use of a direct synthetic route to obtain polymer‐grafted Cu(II)‐based metal–organic polyhedra gives rise to a low‐cost and scalable cage. This material combines low‐temperature melting, achieving phase changes while preserving cage integrity, and high CO2 uptake exceeding 0.6 mmol g−1.
Alba Cortés‐Martínez +6 more
wiley +1 more source
Rh(III)-Catalyzed [4 + 2] Spiroannulation of 2-Phenylbenzimidazoles with Isomerizable 3-Methylmaleimides: Synthesis of Spiro-Fused Benzimidazoisoquinoline Succinimides. [PDF]
Chiu WJ, Shih MH, Barve IJ, Sun CM.
europepmc +1 more source
Butterfly wing–inspired intrinsically self‐healing polymer interlayers enable flexible perovskite optoelectronics with high luminance, strain‐insensitive stability, and environmental resilience. These hierarchically structured films redistribute mechanical stress, suppress defect formation, and maintain performance under repeated bending, paving the ...
Loganathan Veeramuthu +13 more
wiley +1 more source
Di-Silyl Rhodium(III) and Iridium(III) Complexes as Catalysts in Carbene Insertion Reactions into Hydrosilanes. [PDF]
Azpiazu-Galarza A +4 more
europepmc +1 more source
Cobalt‐Catalyzed Asymmetric Construction of Boron Stereocenters With C–N Axial Chirality
A cobalt/Salox‐catalyzed one‐pot annulation enables enantioselective formation of B‐stereogenic centers and C─N axial chirality via C─H/N─H annulation, affording diverse fluorescent products with high stereocontrol and optoelectronic potential. ABSTRACT The efficient construction of boron stereogenic centers alongside axial chirality remains a ...
Subramani Kumaran +5 more
wiley +1 more source

