Divergent synthesis of indenoisoquinolines and indenoisochromenes by rhodium-catalysed cyclocondensation of <i>N</i>-substituted benzamides with 2-diazoindenediones. [PDF]
Kim DY, Kimura Y, Miura R, Kondo T.
europepmc +1 more source
Precise characterization of n‐type organic semiconductors necessitates decoupling interfacial constraints from intrinsic charge transport. This work reveals that disordered polymers are particularly vulnerable to contact‐limited bottlenecks compared to their crystalline counterparts.
Walid Boukhili +15 more
wiley +1 more source
Mitochondria-targeting cyclometallated rhodium(iii) complexes appended with two rhodamine units as Type I photosensitisers for bioimaging and photocytotoxicity applications by inducing pyroptosis. [PDF]
Jiang KG +6 more
europepmc +1 more source
NiH‐Catalyzed Enantio‐ and Regioselective Hydroselenylation of Unactivated Alkenes
Nickel‐hydride‐catalyzed enantio‐ and regioselective hydroselenylation of unactivated alkenes provides access to chiral organoselenium compounds. Enantiodetermining Ni–H insertion followed by single‐electron diselenide activation generates selenyl radical.
Hyung‐Joon Kang +2 more
wiley +1 more source
Atomic-Scale Understanding of Doping Effects in BaTiO<sub>3</sub> in the Presence of Water: Implications for Photocatalytic Water Splitting. [PDF]
Zakiyeva ZY +10 more
europepmc +1 more source
Orientation‐Engineered Insulator‐Metal Transition in Vanadium Dioxide
Crystallographic orientation engineering in VO2/TiO2 heterostructures enables tunable insulator‐metal transitions. The high‐Miller‐index (102) orientation breaks in‐plane mirror symmetry, inducing anisotropic transport, while its inclined oxygen channels accelerate protonation kinetics.
Xuanchi Zhou +4 more
wiley +1 more source
Introducing Diradicaloid Thiele's Hydrocarbon Derivatives as Ligand in Transition Metal Chemistry. [PDF]
Mahata A, Neuman NI, Sarkar B.
europepmc +1 more source
Electric‐field‐controlled antiferroelectric switching offers a ferroic pathway for reversible interconversion between symmetry‐distinct antiferromagnetic states in a two‐dimensional halide perovskite. A spin‐split altermagnet transforms into a spin‐degenerate type‐IV antiferromagnet through field‐driven structural symmetry reconstruction, enabling ...
Wan Zhao +7 more
wiley +1 more source
Triflate-Enabled Rhodium-Catalyzed Cross-Dehydrogenative Si-N Bond Formation from Hydrosiloxanes. [PDF]
Padilla M +4 more
europepmc +1 more source
A conductive ZrB2 ceramic composite strategy was developed for Mg3(Sb, Bi)2 thermoelectrics to regulate carrier transport and phonon scattering through heterointerface engineering. The 1.0 wt.% ZrB2 composite achieved enhanced room‐temperature performance, with a power factor of 28.51 µW cm−1 K−2 and a peak ZT of 1.22 at 573 K.
Yangyang Xu +7 more
wiley +1 more source

