Results 21 to 30 of about 938,190 (242)

Hoveyda–Grubbs catalysts with an N→Ru coordinate bond in a six-membered ring. Synthesis of stable, industrially scalable, highly efficient ruthenium metathesis catalysts and 2-vinylbenzylamine ligands as their precursors

open access: yesBeilstein Journal of Organic Chemistry, 2019
A novel and efficient approach to the synthesis of 2-vinylbenzylamines is reported. This involves obtaining 2-vinylbenzylamine ligands from tetrahydroisoquinoline by alkylation and reduction followed by the Hofmann cleavage.
Kirill B. Polyanskii   +6 more
doaj   +1 more source

First Total Synthesis of Cryptopyranmoscatone A3 and Crypto­pyranmoscatone B4

open access: yesSynOpen, 2018
The first total synthesis of cryptopyranmoscatones A3 and B4 has been accomplished from d-ribose or but-3-ynol. The key steps involved in the synthesis are oxa-Michael addition, highly diastereo­selective Brown allylation, and ring closing metathesis ...
A. Maheswara Reddy, Gowravaram Sabitha
doaj   +1 more source

Stereoselectivity of Macrocyclic Ring-Closing Olefin Metathesis [PDF]

open access: yesOrganic Letters, 2000
[reaction: see text] Macrocyclic ring-closing olefin metathesis using ruthenium catalyst 3 was performed to produce a 14-membered lactone. The E/Z ratio of lactone was high regardless of the R group (auxiliary) or the initial alkene stereochemistry.
Lee, Choon Woo, Grubbs, Robert H.
openaire   +4 more sources

A New Variant of Fused Cyclic Ether Synthesis Based on Ireland-Claisen Rearrangement and RCM

open access: yesNatural Product Communications, 2013
A new variant of fused cyclic ether synthesis based on Ireland-Claisen rearrangement and ring-closing olefin metathesis (RCM) was developed. The Ireland-Claisen rearrangement and ring-closing olefin metathesis (RCM) was developed.
Daisuke Domon   +5 more
doaj   +1 more source

Light-induced olefin metathesis

open access: yesBeilstein Journal of Organic Chemistry, 2010
Light activation is a most desirable property for catalysis control. Among the many catalytic processes that may be activated by light, olefin metathesis stands out as both academically motivating and practically useful.
Yuval Vidavsky, N. Gabriel Lemcoff
doaj   +1 more source

Polycyclic Aromatic Hydrocarbons by Ring‐Closing Metathesis. [PDF]

open access: yesChemInform, 2005
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access the actual ChemInform Abstract, please click on HTML or PDF.
Margel C, Bonifacio   +3 more
openaire   +2 more sources

Ring Rearrangement Metathesis in 7-Oxabicyclo[2.2.1]heptene (7-Oxanorbornene) Derivatives. Some Applications in Natural Product Chemistry

open access: yesNatural Product Communications, 2017
Metathesis reactions is firmly established as a valuable synthetic tool in organic chemistry, clearly comparable with the venerable Diels-Alder and Wittig reactions and, more recently, with the metal-catalyzed cross-coupling reactions.
Silvia Roscales, Joaquín Plumet
doaj   +1 more source

Tandem Catalytic Asymmetric Ring-Opening Metathesis/Ring-Closing Metathesis

open access: yes, 2016
Tandem Catalytic Asymmetric Ring-Opening Metathesis/Ring-Closing ...
Richard R. Schrock (1295601)   +4 more
core   +1 more source

Tandem Cyclopropanation/Ring-Closing Metathesis of Dienynes

open access: yes, 2016
Certain dienynes give cyclorearrangement by tandem cyclopropanation/ring-closing alkene metathesis, triggered by either a ruthenium carbene or noncarbene ruthenium(II) precatalyst.
Steven T. Diver (1667287)   +1 more
core   +1 more source

Ring-Opening/Ring-Closing Metathesis (RORCM) Reactions of 7-Azanorbornene Derivatives. An Entry into Perhydroindolines

open access: yes, 2016
7-Azanorbornenes undergo ring-opening/ring-closing metathesis upon treatment with the second-generation Grubbs catalyst to give hexahydroindoline ...
Jon D. Rainier (1688194)   +1 more
core   +2 more sources

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