Results 81 to 90 of about 938,190 (242)

Rapid, two-pot procedure for the synthesis of dihydropyridinones; total synthesis of aza-goniothalamin

open access: yesBeilstein Journal of Organic Chemistry, 2020
A fast, protecting-group-free synthesis of dihydropyridinones has been developed. Starting from commercially available aldehydes, a novel one-pot amidoallylation gave access to diene compounds in good yields.
Thomas J. Cogswell   +2 more
doaj   +1 more source

A short stereoselective synthesis of (+)-(6R,2′S)-cryptocaryalactone via ring-closing metathesis

open access: yesBeilstein Journal of Organic Chemistry, 2009
A short stereoselective synthesis of (+)-(6R,2′S)-cryptocaryalactone was successfully completed. Key steps included the application of Carreira’s asymmetric alkynylation reaction to form a propargylic alcohol and subsequently lactone formation using the ...
Palakodety Radha Krishna   +2 more
doaj   +1 more source

Synthesis of cyclic proline-containing peptides via ring-closing metathesis

open access: yes, 2003
Several dienes embedded in di- and tripeptides which incorporate proline have been prepared and subjected to ring-closing metathesis. Bicyclic peptides of well-defined amide geometry and of varying ring sizes were prepared.
Brimble, MA   +5 more
core   +1 more source

Activation of Metal Complexes With Ultrasound Waves for Targeted Anticancer Therapy

open access: yesAngewandte Chemie International Edition, EarlyView.
Ultrasound enables non‐invasive activation of metal‐based therapeutics deep within tumors. Acoustic cavitation can drive sonodynamic reactive oxygen species generation or mechanochemical metal–ligand bond dissociation, enabling controlled release of bioactive payloads.
Félix Grosjean   +3 more
wiley   +1 more source

Design principles for vitrimers: Linking dynamic covalent chemistry, network architecture, and engineering performance

open access: yesBulletin of the Korean Chemical Society, EarlyView.
This review examines vitrimer performance from a broader perspective, considering not only dynamic covalent chemistry but also molecular structure, network architecture, and rheological behavior. These factors are discussed in relation to service and processing windows, reprocessing, repair, and engineering applications, providing a multiscale ...
Kyosun Ku, Hyeonuk Yeo
wiley   +1 more source

Molybdenum‐carbothioamide complexes as potential single‐source precursors for MoS2 thin film

open access: yesBulletin of the Korean Chemical Society, EarlyView.
Novel molybdenum complexes were synthesized to apply for deposition of Mo‐containing thin films. All complexes were characterized, and they are likely to be used as single‐source precursors for MoS2 thin films. Abstract Molybdenum disulfide (MoS2) thin films are widely used in batteries, transistors, supercapacitors, and 2D materials owing to their ...
Sung Kwang Lee   +3 more
wiley   +1 more source

Hybrid macrocycle formation and spiro annulation on cis-syn-cis-tricyclo[6.3.0.02,6]undeca-3,11-dione and its congeners via ring-closing metathesis

open access: yesBeilstein Journal of Organic Chemistry, 2015
We have developed a simple methodology to transform cis-syn-cis-triquinane derivative 2 into the diindole based macrocycle 6 involving Fischer indolization and ring-closing metathesis (RCM).
Sambasivarao Kotha   +2 more
doaj   +1 more source

Phosphanyl Radicals From Bismuth‐Mediated Reactions and Sterically Encumbered Diphosphanes

open access: yesChemistry – A European Journal, EarlyView.
Reactions of LiPR2 with BiCl3 selectively give diphosphanes R2P–PR2 in high yields, presumably via Bi─P homolysis. This includes challenging cases with bulky substituents R. Sterically encumbered diphosphanes release persistent phosphanyl radicals [PR2]• in thermally initiated equilibrium reactions.
Sascha Reith   +3 more
wiley   +1 more source

Tandem Glycolate Claisen Rearrangement/Ring-Closing Metathesis:  A Stereochemically General Synthesis of Substituted Dihydropyran-2-carboxylates

open access: yes, 2016
Tandem Glycolate Claisen Rearrangement/Ring-Closing Metathesis:  A Stereochemically General Synthesis of Substituted Dihydropyran-2 ...
James A. Morrison (3043614)   +3 more
core   +2 more sources

Nitro-Grela-type complexes containing iodides – robust and selective catalysts for olefin metathesis under challenging conditions

open access: yesBeilstein Journal of Organic Chemistry, 2015
Iodide-containing nitro-Grela-type catalysts have been synthesized and applied to ring closing metathesis (RCM) and cross metathesis (CM) reactions. These new catalysts have exhibited improved efficiency in the transformation of sterically, non-demanding
Andrzej Tracz   +3 more
doaj   +1 more source

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