Synthesis and Thermolysis of Ylidyl‐Substituted Stannylenes
Zeitschrift für anorganische und allgemeine Chemie, EarlyView.The synthesis of an amino(ylidyl)stannylene is reported. The title compound was characterized via X‐ray diffraction and features a Sn2C2 heterocycle. Thermal treatment of the stannylene leads to the elimination of the amine. The products of the thermolysis are discussed.
Pascal Weisenburger +3 more
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Synthesis of Substituted Tetrafluorocyclobutenes and Their Ring-Opening Metathesis/Ring-Closing Metathesis to Dihydrofurans Bearing a Tetrafluoroethylene Unit. [PDF]
ACS OmegaKučnirová K +3 more
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Cross Carbonyl‐Olefin Metathesis of Unactivated Olefins
Advanced Synthesis &Catalysis, Volume 368, Issue 13, 2 July 2026.A method for the olefination of aryl aldehydes with unactivated alkenes via cross carbonyl‐olefin metathesis is described. Reaction of an aldehyde substrate with a cis−1,2‐disubstituted or monosubstituted olefin using the HBF4 salt of 2,3‐diazabicyclo[2.2.2]octane results in high‐yielding olefination with exclusive trans stereoselectivity. The reaction
Jason Wu +2 more
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Programmable Artificial-Cellular Membrane Dynamics via Ring-Closing Metathesis. [PDF]
J Am Chem SocHamaguchi R +3 more
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Advanced Synthesis &Catalysis, Volume 368, Issue 13, 2 July 2026.Combining dichloro and diiodo ruthenium catalysts produces mixed chloro–iodo species via in situ halide exchange, resulting in a new, more efficient catalytic system. The mixed catalysts outperform their homo‐anionic counterparts, delivering enhanced activity, higher conversion, and strong suppression of isomerization under both thermal and ...
Nebal Alassad +3 more
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Efficient convergent synthesis of 1,3-diazepinone nucleosides by ring-closing metathesis and direct glycosylation. [PDF]
RSC AdvHedger AK +5 more
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Optimized Ring Closing Metathesis Reaction Conditions To Suppress Desallyl Side Products in the Solid-Phase Synthesis of Cyclic Peptides Involving Tyrosine(O-allyl). [PDF]
J Org Chem, 2020 Gisemba SA, Aldrich JV.
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The Versatile Structural World of Methanedi‐ and Trisulfonic Acid and Their Salts
ChemistryOpen, Volume 15, Issue 7, July 2026.The solid‐state structures of the CH4‐derived polysulfonic acids methanedisulfonic acid (MDSA) and methanetrisulfonic acid (MTSA) are presented for the first time. Additionally, a broad overview over possible MDS and MTS salts, containing mostly group I cations, is given and their solid‐state structures are analyzed, showing the structural versatility ...
Katrin Eppers +4 more
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A sequential esterification-ring closing metathesis-Nozaki-Hiyama-Kishi strategy for constructing a natural product-like library of tetrahydrofuran-containing macrolides. [PDF]
Chem SciDriedger D, Wilson DM, Britton R.
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Chemistry – A European Journal, Volume 32, Issue 24, 23 June 2026.Luminescent coordination polymers of Group 1 (Li, K, Cs) and 2 (Mg─Ba) cations with gold(I) iso‐maleonitriledithiolate ({Au2[S2C = C(CN)2]}2−) units were prepared; 1‐D aurophilic chains are present in all cases. The structures strongly depend on cation charge and size, with N‐cyano coordination observed in the Gp 1 and larger Gp 2 cations. Increasingly
Jefferson A. Pells +2 more
wiley +1 more source