Results 81 to 90 of about 9,389 (255)

Ring-Closing Metathesis of N-Alkenyl-Cyanamides

open access: yes, 2021
An entry to new classes of nitrogen-containing heterocycles featuring both a cyanamide and an unsaturated 5-, 6- or 7- membered ring is reported. They can be readily obtained by ring-closing metathesis of the corresponding N-alkenyl-cyanamides – new ...
Diacofotaki, Christina   +2 more
core   +1 more source

A short stereoselective synthesis of (+)-(6R,2′S)-cryptocaryalactone via ring-closing metathesis

open access: yesBeilstein Journal of Organic Chemistry, 2009
A short stereoselective synthesis of (+)-(6R,2′S)-cryptocaryalactone was successfully completed. Key steps included the application of Carreira’s asymmetric alkynylation reaction to form a propargylic alcohol and subsequently lactone formation using the ...
Palakodety Radha Krishna   +2 more
doaj   +1 more source

Enamide−Olefin Ring-Closing Metathesis

open access: yes, 2016
The first examples of ring-closing metathesis reactions of olefin-containing enamides using ruthenium-based catalysts have been demonstrated. A preliminary investigation into the scope and limitations, leading to protected five- and six-membered cyclic ...
Jan H. van Maarseveen (1489900)   +4 more
core   +1 more source

Heptane-Soluble Ring-Closing Metathesis Catalysts

open access: yes, 2016
Terminally vinyl-functionalized polyisobutylene (PIB) oligomers can be easily transformed into end-functionalized PIB-bound Ru metathesis catalysts. The nonpolar catalysts so prepared can be used as solutions in heptane and recycled by a gravity-based ...
David E. Bergbreiter (1544338)   +3 more
core   +1 more source

Hybrid macrocycle formation and spiro annulation on cis-syn-cis-tricyclo[6.3.0.02,6]undeca-3,11-dione and its congeners via ring-closing metathesis

open access: yesBeilstein Journal of Organic Chemistry, 2015
We have developed a simple methodology to transform cis-syn-cis-triquinane derivative 2 into the diindole based macrocycle 6 involving Fischer indolization and ring-closing metathesis (RCM).
Sambasivarao Kotha   +2 more
doaj   +1 more source

Molybdenum-Catalyzed Ring-Closing Metathesis of Allenynes

open access: yes, 2016
A ring-closing metathesis reaction of allenynes occurred at room temperature in the presence of a molybdenum alkylidene complex to give ring-closed vinylallenes.
Masahiro Murakami (8477)   +2 more
core   +1 more source

Hydroxycyclopentanone derivatives from D-Mannose via ring closing metathesis: An improved synthesis of a key intermediate of Tricyclo-DNA

open access: yes, 2003
A large scale, 10 step synthesis of cyclopentanone 1 , starting from the chiral pool compound D-mannose, is described. The synthesis proceeds via a ring closing metathesis reaction as the key step in an overall yield of 23%.
Leumann, Christian, Vonlanthen, David
core   +1 more source

Nitro-Grela-type complexes containing iodides – robust and selective catalysts for olefin metathesis under challenging conditions

open access: yesBeilstein Journal of Organic Chemistry, 2015
Iodide-containing nitro-Grela-type catalysts have been synthesized and applied to ring closing metathesis (RCM) and cross metathesis (CM) reactions. These new catalysts have exhibited improved efficiency in the transformation of sterically, non-demanding
Andrzej Tracz   +3 more
doaj   +1 more source

Synthesis of 1,2-Dihydroquinolines via Hydrazine-Catalysed Ring-Closing Carbonyl-Olefin Metathesis

open access: yes, 2019
The synthesis of 1,2-dihydroquinolines by the hydrazine-catalysed ring-closing carbonyl-olefin metathesis (RCCOM) of N-prenylated 2-aminobenzaldehydes is reported.
Tristan, Lambert   +3 more
core   +1 more source

A Concise and Stereoselective Total Synthesis of Paecilomycin E

open access: yesNatural Product Communications, 2019
A concise approach for the first total synthesis of paecilomycin E is described involving Alder-Rickert reaction, Mitsunobu esterification and ring closing metathesis as the key steps.
A. Srinivas Reddy   +4 more
doaj   +1 more source

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