Results 51 to 60 of about 5,195 (200)

Thermally triggered polyrotaxane translational motion helps proton transfer

open access: yesNature Communications, 2018
Proton exchange is critical in many applications, such as in conductive proton exchange membranes, but achieving fast proton exchange still remains a challenge.
Xiaolin Ge   +7 more
doaj   +1 more source

A Rotaxane Exciplex

open access: yes, 2016
A Rotaxane ...
Timothy M. Swager (1308438)   +2 more
core   +2 more sources

Cyclodextrin-based rotaxanes for polymer materials: challenge on simultaneous realization of inexpensive production and defined structures

open access: yesBeilstein Journal of Organic Chemistry
Owing to their dynamic natures, rotaxane-based polymers are attractive motifs for developing stimuli-responsive materials. However, the accurate control of the rotaxane structure, which can be achieved via multistep synthesis, is key to utilizing the ...
Yosuke Akae
doaj   +1 more source

Azo‐Dye Rotaxanes

open access: yesAngewandte Chemie International Edition in English, 1997
The hydrophobic effect was used to assemble encapsulated azo dyes such as 1 in water. The dumbbell-shaped dyes were synthesized inside α-cyclodextrin, β-cyclodextrin, or a cyclophane to yield stable rotaxanes.
Anderson, S, Claridge, T, Anderson, H
openaire   +1 more source

Multiply threaded rotaxanes [PDF]

open access: yesSupramolecular Chemistry, 2018
Mechanically interlocked molecules (MIMs) of all shapes and sizes are available to Chemists, driving forward progress across a broad range of research areas.
openaire   +3 more sources

Rotaxane for Molecular Electronics Applications

open access: yes, 2023
UB RISE 2023, Department of Computer Science and Engineering, University of Bridgeport. Department of Biomedical and Mechanical Engineering, University of Bridgeport.
Wu, Peiqiao   +3 more
core  

Stepwise, Protecting Group Free Synthesis of [4]Rotaxanes

open access: yesMolecules, 2017
Despite significant advances in the last three decades towards high yielding syntheses of rotaxanes, the preparation of systems constructed from more than two components remains a challenge.
James E. M. Lewis   +2 more
doaj   +1 more source

Rotaxanes with dynamic mechanical chirality: Systematic studies on synthesis, enantiomer separation, racemization, and chiral-prochiral interconversion

open access: yesFrontiers in Chemistry, 2022
Dynamic mechanical chirality of [2]rotaxane consisting of a Cs symmetric wheel and a C2v symmetric axle is discussed via the synthesis, enantiomer separation, racemization, and chiral-prochiral interconversion.
Fumitaka Ishiwari   +3 more
doaj   +1 more source

Thermoresponsive Shuttling of Rotaxane Containing Trichloroacetate Ion

open access: yes, 2016
A thermoresponsive rotaxane shuttling system was developed with a trichloroacetate counteranion of an ammonium/crown ether-type rotaxane. Chemoselective thermal decomposition of the ammonium trichloroacetate moiety on the rotaxane yielded the ...
Yoko Abe (1838848)   +5 more
core   +1 more source

Rotaxane: a switching element in molecular electronics

open access: yesBibechana, 2010
The switching in materials is the most interesting phenomenon discovered in materials, both organic and inorganic. The switching materials opened a large class of applications in electronics and informatics.
NK Chaudhary
doaj   +3 more sources

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