Results 61 to 70 of about 5,195 (200)
Chemistry – A European Journal, EarlyView.This research presents a novel 1,4‐π‐functionalized calix[6]arene with enhanced interactions with dialkylammonium axles. We investigate threading behavior in CDCl3, highlighting how exo‐rim π‐functionalization affects binding affinity and stereoselectivity.
Veronica Iuliano +7 more
wiley +1 more source
A Redox-Controllable Molecular Switch Based on Weak Recognition of BPX26C6 at a Diphenylurea Station
Molecules, 2015 The Na+ ion–assisted recognition of urea derivatives by BPX26C6 has allowed the construction of a redox-controllable [2]rotaxane-type molecular switch based on two originally very weakly interacting host/guest systems.
Jia-Cheng Chang +2 more
doaj +1 more source
Nature Communications, 2022 Amplifying molecular motion to macroscopic material property is attractive but challenging. Here, the authors report mechanically interlocked networks with dense rotaxane backbones whose microscopic motion is integrated into decent mechanical properties ...
Xue Yang +7 more
doaj +1 more source
Heterovalent, Homometallic Rings: Synthesis, Optical, and EPR Studies of {TiIV7TiIII} Complexes
Chemistry – A European Journal, EarlyView.A new class of heterovalent, homometallic complexes is reported, based on cyclic {TiIV7TiIII} cores with oxide and carboxylate bridges between nearest neighbors. The clusters show Class II mixed‐valent behavior at room temperature, but are valence localized at low temperature.
Selena J. Lockyer +8 more
wiley +1 more source
Chemistry – A European Journal, EarlyView.The rotaxane architecture is a powerful tool to probe weak interactions. The interaction between the ring component and the axle components was estimated by quantitative conformational analysis of the rotaxanes by 1H NMR spectroscopy. Theoretical calculations revealed that C─H⋯N interactions and steric effects would be responsible for the preferred ...
Taichi Ohseki +6 more
wiley +1 more source
, 2014 Citation: 'rotaxanes' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.R05416 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
openaire +1 more source
Scaling Up Molecular Electron Spin Qubits Around a Core‐Shell Quantum Dot
Chemistry – A European Journal, EarlyView.Making assemblies of molecular nanomagnet (MNM) qubits is an essential step toward scalable quantum devices. Here, SH‐functionalized {Cr7Ni} antiferromagnetic rings with ability as MNM qubits were successfully grafted to the surface of fluorescent CdSe/ZnS quantum dots (QD).
Simon G. McAdams +8 more
wiley +1 more source
MolbankOligo(phenylene ethynylene)s (OPEs) are π-conjugated systems with promising optical, bioactive, and electrical properties, making them valuable candidates for molecular electronics and biosensors.
Susumu Tsuda +3 more
doaj +1 more source
Diverse reactivity of maleimides in polymer science and beyond
Polymer International, Volume 74, Issue 4, Page 296-306, April 2025.This mini‐review provides a thorough overview of maleimide chemistry, highlighting its diverse reactivity in polymer and materials science applications. Abstract Maleimides are remarkably versatile functional groups, capable of participating in homo‐ and copolymerizations, Diels–Alder and (photo)cycloadditions, Michael additions, and other reactions ...
Bruce E Kirkpatrick +2 more
wiley +1 more source
Cyclodextrin Rotaxanes of Pt Complexes and Their Conversion to Pt Nanoparticles
Molecules, 2020 The cationic Pt complex (Pt(NC6H4-C6H4N-(CH2)10-O(C6H3-3,5-(OMe)2)(MeN-(CH2CH2NMe2)2))+ was prepared by the reaction of alkylbipyridinium ligand with a nitrateplatinum(II) complex.
Yuji Suzaki +2 more
doaj +1 more source