Results 71 to 80 of about 5,195 (200)
The Chemical Record, EarlyView.This Personal Account discusses how molecular simulations help uncover motion, shuttling mechanisms, and kinetics in mechanically interlocked molecules such as rotaxanes and catenanes. Mechanically interlocked molecules, such as rotaxanes and catenanes, display complex internal dynamics and reciprocal motions that are central to their use as artificial
Clara Sabrià +6 more
wiley +1 more source
Statistical Mechanics of Rotaxane Switches [PDF]
, 2019 A solution of rotaxane switches, which can switch their length by external stimuli, is described using statistical thermodynamics. We show that this solution can exhibit different behaviors.
He, Hao
core +1 more source
ReactionsTo explore new possibilities in topological materials, we designed a tetrafunctional crosslinker composed of a [c2]daisy-chain rotaxane framework. In this study, a novel topological network polymer was successfully synthesized via an addition reaction ...
Yuuki Kawashima +3 more
doaj +1 more source
Chemistry – A European JournalOrganic cages are a robust class of molecular hosts with a myriad of applications in materials science. Despite this, there has been a paucity of explorations into the modification of their properties via external functionalization. In this work, [n]rotaxanes featuring unoccupied organic cages as stopper components and a small 2,2’-bipyridine ...
Zarik Zaheer Yusaf +5 more
openaire +2 more sources
Smart molecules for imaging, sensing and health (SMITH)
Beilstein Journal of Organic Chemistry, 2015 This autobiographical review provides a personal account of the author’s academic journey in supramolecular chemistry, including brief summaries of research efforts in membrane transport, molecular imaging, ion-pair receptors, rotaxane synthesis ...
Bradley D. Smith
doaj +1 more source
Aggregate, Volume 7, Issue 9, September 2026.This review summarizes the latest progress of RTP materials with self‐healing and shape–memory functions, in which reversible bonding interactions are the key points. With the careful discussions of the typical strategies and representative works, the intrinsic relationship between dynamic bonding interactions and RTP property is well revealed. Finally,
Dan Li, Jie Yang, Zhen Li
wiley +1 more source
Stretchable poly[2]rotaxane elastomers
Fundamental Research: Mechanically interlocked polymers (MIPs) are promising candidates for the construction of elastomeric materials with desirable mechanical performance on account of their abilities to undergo inherent rotational and translational mechanical movements at
Kai Liu +9 more
doaj +1 more source
European Journal of Organic Chemistry, Volume 29, Issue 33, 1 September 2026.Catechol‐based annulated aromatics with carbonyl units are ideal ligands for the formation of titanium(IV) containing lithium‐bridged hierarchical helicates. They allow for the first time the use of amide units to obtain the dimeric helicate‐type complexes.
Steffen Schauerte +4 more
wiley +1 more source
1,2,3-Triazolium macrocycles in supramolecular chemistry
Beilstein Journal of Organic Chemistry, 2019 In this short review, we describe different pathways for synthesizing 1,2,3-triazolium macrocycles and focus on their application in different areas of supramolecular chemistry.
Mastaneh Safarnejad Shad +2 more
doaj +1 more source
Macromolecular Rapid Communications, Volume 47, Issue 17, 4 September 2026.Triacetylated γ‐cyclodextrin incorporated into poly(methyl methacrylate) primarily acted as a rigid filler and reinforced the matrix polymer, with the reinforcement behavior following the Guth–Gold equation. In addition, the glass transition temperature was maintained upon incorporation, indicating that the additive did not plasticize the polymer ...
Rinsei Toda +2 more
wiley +1 more source