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Effect of rotenoids from the seeds ofMillettia dura on larvae ofAedes aegypti
A crude chloroform extract of seeds of Millettia dura Dunn (Leguminosae) showed high activity (LC50 = 3.5 µg ml−1 at 24 h) against second-instar larvae of the mosquito, Aedes aegypti L (Diptera: Culicidae). The rotenoids, deguelin and tephrosin, isolated
Abiy Yenesew +2 more
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NMR investigations of rotenoids
Tetrahedron, 1973Abstract Extensive NMR studies of major rotenoids have (1) verified the cis B/C ring fusion of rotenone; (2) confirmed the structure of the reduction-dehydration product of rotenone; (3) provided considerable evidence regarding the preferred conformations of rotenoids; (4) revealed an array of long-range couplings; and (5) pointed up analytically ...
D.G. Carlson, D. Weisleder, W.H. Tallent
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Rotenoids from roots of Clitoria Fairchildiana
Phytochemistry, 1998A new rotenoid, named 9-demethylclitoriacetal, together with the known compounds, 11-deoxyclitoriacetal, 6-deoxyclitoriacetal, clitoriacetal and stemonal, was isolated from roots of Clitoria fairchildiana. Its structure was elucidated as 6a,12a-dihydro-6,9,11,12a-tetrahydroxy-2,3-dimethoxy-[1]benzopyrano[3,4-b] [1]benzopyran-12(6H)-one (1), on the ...
Bernadete P., Silva +2 more
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Optical resolution of rotenoids
Journal of Heterocyclic Chemistry, 1987AbstractOptical resolution of selected rotenoids containing 1‐3 asymmetric centers in dihydrobenzopyranofuroben‐zopyranone and dihydrobisbenzopyranopyranone series has been achieved on two chiral high‐performance liquid chromatographic (hplc) stationary phases.
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Preparation of synthetic rotenoids
Experientia, 1975Eine einfache Synthese von Rotenoiden durch Kondensation von 4-Ethoxycarbonyl-3-chromanonen mit Phenolen und katalytischer Hydrierung der entstehenden Dehydrorotenoide wird beschrieben.
R. Verhé, N. Schamp
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Reactions of rotenoids with hydroxylamine
Liebigs Annalen der Chemie, 1988AbstractReaction of rotenone (1a) and amorphigenin (2a) with hydroxylamine in alkaline medium affords a mixture of the isoximes 5 and 6, and the new 6a‐NH2 spiro derivatives 12a, b and 13a, b. The structures, stereochemistry, and the mechanisms of formation of these products are discussed.
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Rotenoids from Amorpha canescens
Transactions of the Kansas Academy of Science (1903-), 1979recovered no rotenoids. Elution (6-8 column volumes) with 1:3 EtOAc/hexane recovered all rotenoid materials. The solvent was evaporated and the residue analyzed by TLC (Delfel, 1966) and HPLC (Moring, 1977). Direct comparison with standards suggested the presence of rotenone, degulin, tephrosin, and rotenolone. Peaks with retention volumes of rotenone,
Stephen E. Moring, James D. McChesney
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Novel N-containing rotenoid and seco-rotenoid from the root of Derris elliptica
Journal of Asian Natural Products Research, 2009Two new rotenoids, 2-hydroxy-5-aminorotenonone (1) and elliptoic acid (2), were isolated from the roots of Derris elliptica collected in Guangdong Province, China. Their structures were established by extensive spectral analysis. Compound 1 is the first N-containing rotenoid and compound 2 is the third rotenoid with the cleavage of C(12)-C(12a).
Hai-Ying, Lu, Jing-Yu, Liang
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Rotenoids from Boerhaavia repens
Phytochemistry, 1990Abstract Two new rotenoid derivatives have been identified from Boerhaavia repens . The structures were elucidated by high field 1 H NMR techniques.
Maniruddin Ahmed +2 more
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