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Rotenoidsの化学

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Antiinflammatory activity of rotenoids from Clitoria fairchildiana

Phytotherapy Research, 2002
Five structurally related rotenoids were isolated from the roots of Clitoria fairchildiana. The antiinflammatory activity was investigated using a capillary permeability assay. The protective effect was measured as the inhibition in vascular permeability produced by acetic acid in the peritoneal cavity. The results suggest that for maximum activity the
JOSÉ Parente
exaly   +3 more sources

NMR investigations of rotenoids

Tetrahedron, 1973
Abstract Extensive NMR studies of major rotenoids have (1) verified the cis B/C ring fusion of rotenone; (2) confirmed the structure of the reduction-dehydration product of rotenone; (3) provided considerable evidence regarding the preferred conformations of rotenoids; (4) revealed an array of long-range couplings; and (5) pointed up analytically ...
D.G. Carlson, D. Weisleder, W.H. Tallent
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Preparation of synthetic rotenoids

Experientia, 1975
Eine einfache Synthese von Rotenoiden durch Kondensation von 4-Ethoxycarbonyl-3-chromanonen mit Phenolen und katalytischer Hydrierung der entstehenden Dehydrorotenoide wird beschrieben.
R. Verhé, N. Schamp
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Rotenoid synthesis via radical cyclisation

Journal of the Chemical Society, Chemical Communications, 1988
The (±)-6aα, 12aα, 12α-chromanochromanol acetate (11; R = Ac), representing the core structure of the insecticidal rotenoid alcohol (2), has been synthesised in six steps from the chromone (4); the cis,cis-stereochemistry is obtained in an intramolecular 6-exo aryl radical addition.
S. Asiah Ahmad-Junan, Donald A. Whiting
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Rotenoid diversity, distribution and evolution in plant lineages

Natural Product Reports
This highlight revisits rotenoid classification and provides a thorough understanding of how their occurrences could inform plant taxonomy.
Vaderament-A. Nchiozem-Ngnitedem   +2 more
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Present Status of Rotenone and Rotenoids

Journal of Economic Entomology, 1941
One of the most amazing developments in American agriculture during the past decade has been the rapid growth in the use of derris, cube, timbo, and barbasco as insecticides. These plants, all closely related botanically and belonging to the family Fabaceae, owe their toxicity to rotenone and a group of structurally related compounds called rotenoids.
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[Rotenoids from Derris trifoliata].

Zhong yao cai = Zhongyaocai = Journal of Chinese medicinal materials, 2008
Five rotenoids named dehydrodeguelin, dehydrorotenone, 12a-hydroxy rotenone, tephrosin and 12alphabeta-hydroxyrot-2'-enonic acid were isolated from aerial parts of Derris trifoliata. All these compounds were isolated from this plant for the first time.
Lu-Rong, Xu   +3 more
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