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Electrochemical heteroarylation and amidation of alkanes using activated glassy carbon electrodes without mediators [PDF]

open access: yesCommunications Chemistry
The functionalization of challenging unactivated C(sp 3)–H bonds was achieved electrocatalytically via hydrogen atom transfer and without mediators. This was possible through the sole activation of the surface of the Glassy Carbon Electrode (GCE) in an ...
Loris Laze   +2 more
doaj   +2 more sources

Novel octapeptide containing the RGD sequence as a potential anti-SARS-CoV-2 agent: design, synthesis, and theoretical studies [PDF]

open access: yesAmino Acids
The design of peptide-based inhibitors targeting cell receptors represents a promising strategy in the development of antiviral agents. In this study, a novel octapeptide containing the RGD sequence was rationally designed to explore its potential ...
Reiner Lemos   +6 more
doaj   +2 more sources

Selective Oxidation of Glycerol via Acceptorless Dehydrogenation Driven by Ir(I)-NHC Catalysts

open access: yesMolecules, 2022
Iridium(I) compounds featuring bridge-functionalized bis-NHC ligands (NHC = N-heterocyclic carbene), [Ir(cod)(bis-NHC)] and [Ir(CO)2(bis-NHC)], have been prepared from the appropriate carboxylate- or hydroxy-functionalized bis-imidazolium salts.
M. Victoria Jiménez   +5 more
doaj   +1 more source

Theoretical insight on the treatment of β-hexachlorocyclohexane waste through alkaline dehydrochlorination

open access: yesScientific Reports, 2021
The occurrence of 4.8–7.2 million tons of hexachlorocyclohexane (HCH) isomers stocked in dumpsites around the world constitutes a huge environmental and economical challenge because of their toxicity and persistence.
Alicia Bescós   +4 more
doaj   +1 more source

The Synthesis, Characterization, and Fluxional Behavior of a Hydridorhodatetraborane

open access: yesMolecules, 2023
The octahydridotriborate anion plays a crucial role in the field of polyhedral boron chemistry, facilitating the synthesis of higher boranes and the preparation of diverse transition metal complexes.
Fatou Diaw-Ndiaye   +3 more
doaj   +1 more source

Mini AuAg Wavy Nanorods Displaying Plasmon‐Induced Photothermal and Photocatalytic Properties

open access: yesAdvanced Photonics Research, 2023
Alloyed AuAg wavy nanorods (wNRs) of ≈24.0 nm length and 3.5 nm width are formed by the mild decomposition of the organometallic complex [Au2Ag2(C6F5)4(OEt2)2]n in tetrahydrofuran (THF) in the presence of oleic acid.
Javier Quintana   +6 more
doaj   +1 more source

The synthesis of 4-arylphenalenones revisited

open access: yesResults in Chemistry, 2022
The synthesis of 4-phenylphenalenones, a group of phytoalexins exclusive from Musa acuminata (bananas), has been revisited to extend the scope of the derivatives that can be prepared.
Catalina Hoyos   +3 more
doaj   +1 more source

Spontaneous Water-Promoted Self-Aggregation of a Hydrophilic Gold(I) Complex Due to Ligand Sphere Rearrangement

open access: yesMolecules, 2023
Aggregating gold(I) complexes in solution through short aurophilic contacts promotes new photoluminescent deactivation pathways (aggregation-induced emission, AIE). The time dependence of spontaneous AIE is seldom studied.
Ainhoa Rodríguez-Gobernado   +3 more
doaj   +1 more source

Enantioselective Synthesis of a New Non-Natural Gabosine

open access: yesMolecules, 2021
The preparation of a new non-natural gabosine is reported, in which the chirality is transferred from the toluene’s biotransformed metabolite (1R,2S)-3-methylcyclohexa-3.5-diene-1,2-diol.
Maximiliano Colobbio   +2 more
doaj   +1 more source

Preparation of Mixed Bis-N-Heterocyclic Carbene Rhodium(I) Complexes

open access: yesMolecules, 2022
A series of mixed bis-NHC rhodium(I) complexes of type RhCl(η2-olefin)(NHC)(NHC’) have been synthesized by a stepwise reaction of [Rh(μ-Cl)(η2-olefin)2]2 with two different NHCs (NHC = N-heterocyclic carbene), in which the steric hindrance of both NHC ...
Ramón Azpíroz   +5 more
doaj   +1 more source

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