Results 31 to 40 of about 151,000 (163)
From Light‐Driven to Dark Synthesis: Streamlining Perfluoroalkyl Selenide Ether Formation
Two orthogonal and user‐friendly protocols enable the efficient construction of (Se/S)RF bonds from simple dichalcogenides and perfluoroalkyl iodides. Visible‐light irradiation at 395 nm promotes seleno‐ and thioether formation, while a dark KOH/MeCN variant delivers selenoethers in minutes. Both approaches operate under mild, metal‐ and photocatalyst‐
Loydel Torres Barroso +5 more
wiley +1 more source
Síntesis y estudio fotoquímico de los derivados de 3-(E)-alquenil-4-metoxifenilacetanilidas y 2-(E)-alquenil-4-nitroanisoles [PDF]
This work presents the synthesis and photochemical study of 3-(E)-alkenyl-4-methoxyphenylacetanilide 3a-c and 2-(E)-alkenyl-4-nitroanisole 3d-f derivatives.
Neudo Urdaneta +4 more
doaj
New pyrrolidine-based organocatalysts with a bulky substituent at C2 were synthesized from chiral imines derived from (R)-glyceraldehyde acetonide by diastereoselective allylation followed by a sequential hydrozirconation/iodination reaction.
Alejandro Castán +3 more
doaj +1 more source
La investigación en la Universidad [PDF]
Juan Carlos Rodríguez Ubis: Director del Servicio Interdepartamental de Investigación. Profesor Titular del Departamento de Química Orgánica de la U.A.M. Sus líneas de investigación se centran alrededor de la Química Supramolecular en las que se inició
Rodríguez Ubis, Juan Carlos
core +1 more source
You Spin Me Round. The ligand 1,8‐naphthyridine is able to stabilize heterobimetallic complexes containing Pt(II)→M (M = Ag, Cu) donor–acceptor bonds, in which the rotation of the C6F5 ligands in solution can be stopped at low temperature. The ligand 1,8‐naphthyridine (napy) exhibits a rich coordination chemistry arising from the disposition of its two
Alberto Pérez‐Bitrián +4 more
wiley +1 more source
Glutathione Threshold‐Triggered Selective Breakability of Organosilica Nanocapsules
Replacing tetraethoxy orthosilicate (TEOS) by tetramethoxy orthosilicate (TMOS) as silica precursor to synthesize cleavable organosilica nanocapsules enabled the effective and selective entrapment of a positively charged protein as Cytochrome C (CytC) and a much more favorable breakability and kinetics release when exposed to high glutathione (GSH ...
Andrea Mosseri +5 more
wiley +1 more source
Ginkgo biloba: Antioxidant Activity and In Silico Central Nervous System Potential
Ginkgo biloba (GB) extracts have been used in clinical studies as an alternative therapy for Alzheimer’s disease (AD), but the exact bioaction mechanism has not yet been elucidated. In this work, an in silico study on GB metabolites was carried out using
Eduardo Suárez-González +3 more
doaj +1 more source
Species functional traits affect regional and local dominance across western Amazonian forests
Dominant tree species in western Amazonian forests show distinct functional trait combinations linked to habitat type: conservative traits in stressful habitats and greater plant size in less stressful environments. Local dominants are defined by resource conservation strategies and widespread dominants are defined by resource acquisition strategies. A
Laura Matas‐Granados +45 more
wiley +1 more source
A Homobimetallic Frustrated Lewis Pair Cobalt Catalyst for the Methanolysis of Hydrosilanes
The bimetallic Co(I)/Co(–I) complex [Co(CO)2(κ3‐P,N,P‐PNHP)][Co(CO)4] shows excellent activities in the methanolysis of hydrosilanes, reaching TOF values of ca. 50 000 h−1. This behavior can be ascribed to the presence of the [Co(CO)4]– anion, which allows for a frustrated Lewis pair mechanism, resulting in a low energy pathway for the heterolytic ...
Ana Luque‐Gómez +6 more
wiley +2 more sources
Estudio teórico del mecanismo de reacción de formación de Alumosulfuros y Alumoxanos Ciclicos de cuatro miembros [PDF]
El objetivo más importante de la química, es el estudio de la composición, propiedades y transformación de la materia. Para ello, es necesario conocer a detalle lo que sucede durante una reacción química: el cambio de reactivos a productos. La Química
Cortés Guzmán, Fernando +1 more
core

