Results 221 to 230 of about 2,042,987 (291)

Breaking the Polarity–Coordination Coupling in Electrolyte Design for High‐Voltage Lithium Batteries

Advanced Energy Materials, EarlyView.
Steric and electronic co‐regulation of 2,2,2‐trifluoro‐N, N‐dimethylethylamide (DMTFA) decouples high polarity from strong Li+ coordination, creating an anion‐mediated pseudo‐weakly solvating electrolyte. This design lowers Li+ desolvation barriers, enhances Li+ mobility, and builds B‐, F‐, and N‐rich inorganic interphases, enabling stable 3.0–4.6 V ...
Xue Li, Shangquan Zhao, Yifan Wu, Naigen Zhou, Fei Luo, Runze Liu, Chengjin Peng, Junzhi Li, Stefano Passerini, Shan Fang   +9 more
wiley   +1 more source

Reveal Non‐Uniform Passivation on Lithium Metal Anode With Operando Spectroscopic Ellipsometry

Advanced Energy Materials, EarlyView.
In‐operando spectroscopic ellipsometry reveals how nucleation and crystallographic orientation govern the non‐uniform growth of native passivation films on lithium metal. Time‐resolved thickness mapping captures island formation and coalescence, while orientation‐dependent measurements show that the equilibrium film on Li(110) is approximately half as ...
Jianyu Li, Hanrui Zhang, Dongliang Chen, Feifei Shi   +3 more
wiley   +1 more source

Experimentally Determined Spatiotemporal Charge Carrier Dynamics for the Development of Particulate Photocatalysts

Advanced Energy Materials, EarlyView.
This review looks at the different experimental techniques that measure spatiotemporal charge carrier dynamics. This information is viewed in the context of particulate photocatalysts, outlining the insights these techniques provide and how they advance our understanding.
Sutripto Khasnabis, Robert Godin
wiley   +1 more source

From Data to Discovery: Machine Learning–Enabled Intelligent Characterization of Two‐Dimensional Materials

Advanced Intelligent Discovery, EarlyView.
Machine learning serves as a central engine for the intelligent characterization of two‐dimensional materials by integrating multimodal techniques, including optical microscopy, spectroscopy, electron microscopy, and scanning probe microscopy (SPM). This unified framework enables automated, high‐throughput, and quantitative extraction of structural ...
Zhi‐Long Cao, Jia‐Xu Yan
wiley   +1 more source

Engineering Ferrimagnetic Interactions in Molecular Quantum Systems

Angewandte Chemie, EarlyView.
Heterospin nanographene architectures—constructed by covalently linking spin‐1/2$\nicefrac {1}{2}$ and spin‐1 triangular units via on‐surface synthesis—are characterized by bond‐resolved scanning probe microscopy. Inelastic electron tunneling spectroscopy probes exchange interactions within a Heisenberg model, revealing both compensated (S=0$S=0$) and ...
Elia Turco, Fupeng Wu, Annika Bernhardt, Nils Krane, Ji Ma, Roman Fasel, Michal Juríček, Xinliang Feng, Pascal Ruffieux   +8 more
wiley   +2 more sources

Detection of Microelectromechanical System Acoustics via Scanning Tunneling Microscopy. [PDF]

ACS Nano
Elbertse RJG, Xu M, Keşkekler A, Otte S, Norte RA.   +4 more
europepmc   +1 more source

Accelerating Materials Discovery: A Review of Machine Learning in X‐Ray Absorption Spectroscopy

Advanced Intelligent Systems, EarlyView.
This review systematically details how machine learning transforms X‐ray absorption spectroscopy (XAS) analysis. It covers advanced deep learning architectures for structure‐spectra mapping and inverse tasks, while discussing key challenges like the simulation‐to‐reality gap.
Melaku Lake Tegegne, Haodong Yao, Liyuan Wu, Yihe Pang, Fazhi Qi, Lina Zhao   +5 more
wiley   +1 more source

Tunable Oxygen Connectivity in Carbaporphyrinoid Polymers on Metal Surfaces

Angewandte Chemie, EarlyView.
Hydroxyl‐functionalized dicarbaporphyrinoid polymers synthesized on Au(111) enable tunable oxygen‐mediated connectivity under UHV conditions. Thermal activation yields one‐dimensional hydroxyl‐terminated polymers that can selectively evolve into either covalently‐linked dibenzo‐p‐dioxane architectures through intermolecular C–O–C coupling or two‐fold ...
Alberto Martínez‐Bajo, Maxence Urbani, Ana Barragán, Óscar Jover, Elena Pérez‐Elvira, Ilaria Tomei, Claudio Goletti, Alejandro Jiménez‐Martín, Aurelio Gallardo, Koen Lauwaet, David Écija, Diego Soler‐Polo, Marco Di Giovannantonio, Tomás Torres, José I. Urgel   +14 more
wiley   +2 more sources

Cyclodextrin-Modulated Electrochemical Grafting of Graphite Surfaces with Aryldiazonium Salts. [PDF]

Langmuir
Na HS, Tatsuzawa K, Velpula G, Moriya S, Tamai K, De Feyter S, Tahara K.   +6 more
europepmc   +1 more source

Solvent Hydrogen Bonding Determines Adsorption Geometry of Trimesic Acid on Cu

Angewandte Chemie, EarlyView.
Water reorients adsorbate molecules. Combined tip‐enhanced Raman spectroscopy, density functional theory and molecular dynamics simulations reveal the adsorption geometry of trimesic acid on Cu. Subtle adsorbate–substrate–solvent energy differences due to hydrogen bonding dictate molecular orientation at solid/liquid and solid/gas interfaces, providing
Anusha Lalitha, Qixuan Li, Marialore Sulpizi, Denis Andrienko, Katrin F. Domke   +4 more
wiley   +1 more source