Results 201 to 210 of about 58,719 (283)

Achieving Phonon‐Glass Electron‐Crystal Behavior in Fully Organic Flexible Thermoelectrics

Advanced Energy Materials, EarlyView.
Phonon‐glass Electron‐crystal (PGEC) behavior is demonstrated in fully organic composites consisting of conductive polymers (PEDOT:PSS) and soft polymeric fillers (PVA). The optimized PEDOT:PSS–PVA composite concurrently reveals delocalized transport and thermal conductivity close to its theoretical minimum, yielding a superior thermoelectric figure of
Jeong Han Song, Seunghwan Lee, Sunwoo Cho, Beomsoo Chun, Hyejin Jang, Jeonghun Kwak   +5 more
wiley   +1 more source

Stable Synapse‐Like Memory Switching in N‐Heterocyclic Carbene Monolayers

Angewandte Chemie, EarlyView.
We report a redox‐active N‐heterocyclic carbene (NHC) monolayer showing synapse‐like behavior via proton‐coupled electron transfer (PCET). These quinone‐functionalized NHCs form dense self‐assembled monolayers and highly stable molecular junctions. Bias‐driven PCET switches quinone/hydroquinone states, producing reversible hysteresis and spike‐timing ...
Ankita Das, Alessandro Borrini, Christian Gutheil, Björn Braunschweig, Billura Shakhayeva, Georgios Katsoukis, Ab F. Nieuwenhuis, Raka Ahmed, Susanne Leitherer, Gemma C. Solomon, Frank Glorius, Christian A. Nijhuis   +11 more
wiley   +2 more sources

Observations of Isolated Mobile Au-Br and Au-S Surface Complexes on Au(100) Electrodes. [PDF]

Angew Chem Int Ed Engl
Yang C, Magnussen OM.
europepmc   +1 more source

Molecular Design and Interfacial Functions of Self‐Assembled Monolayers for Perovskite and Tandem Solar Cells

Advanced Energy Materials, EarlyView.
We identify two decisive levers for SAM interfaces: molecular design (carboxylic acid‐based, phosphonic acid, other anchoring chemistries, and polymeric SAMs) and mixing routes (co‐assembly, in situ assembly, pre‐ and post‐treatment). Coordinated tuning of headgroups and assembly pathways optimises energy alignment and film formation, suppresses ...
Jiaxu Zhang, Bochun Kang, Feng Yan
wiley   +1 more source

Spin State in Au Porphyrins Modulated by Charge Transfer on Au(111). [PDF]

J Am Chem Soc
Li D, Kumar M, Stetsovych O, Lowe B, Sengupta R, Hayashi H, Maeda H, Jelínek P, Kawai S.   +8 more
europepmc   +1 more source

Ultra‐Low‐Strain Calcium and Magnesium Ion Storage Enabled by Tunnel‐Structured MoO3 Positive Electrode

Advanced Energy Materials, EarlyView.
A hexagonal tunnel‐structured MoO3 is nanoparticulated via hydrothermal synthesis followed by ball‐milling. As a positive electrode in Ca and Mg batteries, it delivers superior capacity and structural reversibility, enabling divalent cation intercalation with minimal lattice distortion and no phase transitions.
Reona Iimura, M. D. Hashan C. Peiris, Takashi Yabu, Toshihiko Mandai, Ruijie Zhu, Akira Nasu, Saneyuki Ohno, Masaki Matsui, Itaru Honma, Manuel Smeu, Hiroaki Kobayashi   +10 more
wiley   +1 more source

π‐Enlargement in Porphyrin Macrocycles at Interfaces

Angewandte Chemie, EarlyView.
On‐surface synthesis of a 20‐π free‐base expanded porphyrin, by depositing onto a hot Ag(111) substrate an 18‐π free‐base precursor equipped with ‐CF3 functional groups ABSTRACT Porphyrins are essential heteroatomic macrocycles, fundamental to both biological systems and advanced technology.
Ana Barragán, Elena Pérez‐Elvira, Alba García‐Frutos, Diego J. Vicent, Pingo Mutombo, Koen Lauwaet, José M. Gallego, Rodolfo Miranda, José I. Urgel, Aurelio Gallardo, Nazario Martín, David Écija   +11 more
wiley   +2 more sources

Tailored Spin Coupling of Single-Molecule Magnets with a Single Charge-Density-Wave Metal Layer. [PDF]

J Am Chem Soc
Zhang C, Zhou F, Jin H, Zhou L, Dong Z, Ren M, Zhang Q, Yang H, Xu X, Ma YX, Chen L, Jung TA, Huang B, Gao HJ, Zhang Y, Wang Y.   +15 more
europepmc   +1 more source

Device‐Level Implementation of Reservoir Computing With Memristors

Advanced Intelligent Systems, EarlyView.
Reservoir computing (RC) is an emerging computing scheme that employs a reservoir and a single readout layer, which can be actualized in the nanoscale with memristors. As a comprehensive overview, the principles of RC and the switching mechanisms of memristors are discussed, followed by actual demonstrations of memristor‐based RC and the remaining ...
Sunbeom Park, Hyojung Kim, Ho Won Jang
wiley   +1 more source

Radical‐Based On‐Surface Transformation of Nonplanar Aromatics Into Nonbenzenoid Nanographenes

Angewandte Chemie, EarlyView.
Formation of radicals in nonplanar hydrocarbons through thermally induced dehydrogenation leads to molecular transformation via intramolecular radical‐based cyclization and dimerization, leading to formation of nonbenzenoid nanographenes. ABSTRACT On‐surface synthesis has emerged as a powerful tool for atomically precise C─C bond formation, enabling ...
Daniel Rothhardt, Ming‐Lun Pan, Michael Píro, Stefan Niklaus Heinen, Christian Wäckerlin, Hans Josef Hug, Yao‐Ting Wu, Karl‐Heinz Ernst, Miloš Baljozović   +8 more
wiley   +2 more sources