On‐Surface Friedel–Crafts Alkylation Through a Stabilized Intermediate Complex
On‐surface Friedel–Crafts alkylation is demonstrated on Ag(111) at the single‐molecule level. STM, XPS, and DFT calculations uncover the reaction mechanism and explain the stabilization of the key intermediate, providing insight into noble‐metal‐surface‐mediated Csp3${\rm C}_{sp^{3}}$─Csp2${\rm C}_{sp^{2}}$ coupling. ABSTRACT The incorporation of sp3${\
Paul Schweer +5 more
wiley +1 more source
Sliding Ferroelectric Tunnel Junctions with Ultrahigh Tunneling Electroresistance. [PDF]
You H +12 more
europepmc +1 more source
Unraveling the Importance of Surface Hydrogen Diffusion in Photocatalysis by Isotope Probing
Surface hydrogen diffusion on titanium dioxide is identified as a crucial step in photocatalytic hydrogen evolution. Demonstrated by deuterium substitution in methanol, restricted diffusion to the co‐catalyst leads to hindered formation of molecular hydrogen and a high KIE.
Philip Petzoldt +5 more
wiley +1 more source
Potential for detecting a monopole-like topological magnetoelectric response using image potential states. [PDF]
Zhan Y +10 more
europepmc +1 more source
Overview of Research Progress and Development of Cathode Materials for Aqueous Na‐Ion Batteries
ABSTRACT Aqueous sodium‐ion batteries (ASIBs) have now been viewed as the promising energy storage technique for the grid application due to their intrinsic safety and cost‐effectiveness. However, their energy density and cycling stability are still unsatisfactory accompanied by the narrow electrochemical stability window of water and parasitic side ...
Zhiwei Shi +5 more
wiley +1 more source
Entropy plateaus, combinatorial degeneracy, local moments, and heavy-fermion mass renormalization in magic-angle graphene. [PDF]
Zhang Z +7 more
europepmc +1 more source
A multidisciplinary characterization approach combining microscopy, tomography, spectroscopy, and electrical measurements reveals how fiber architecture and network connectivity govern electrical transport in PMMA/rGO microfibers by solution blow spinning.
Clarissa de Paula Dias +8 more
wiley +1 more source
A new era for optical-coupled scanning probe microscopy. [PDF]
Chi L.
europepmc +1 more source
Two‐Dimensional van der Waals Antiferromagnets: Fabrication, Probes, Control, and Applications
Two‐dimensional van der Waals antiferromagnets are emerging as versatile platforms for spintronic, optoelectronic, and quantum devices. This review summarizes recent progress in their fabrication, magnetic characterization, fields, interfacial engineering, chemical modification, and representative applications.
Huangyu Wu +10 more
wiley +1 more source
Electronic‐Structure Control of Ferromagnetism in Fe3GeTe2 and Fe3GaTe2: A Short Review
Fe3GeTe2 and Fe3GaTe2 form a revealing materials pair for examining how carrier filling, orbital hybridization, magnetic anisotropy, and defects cooperate in metallic van der Waals ferromagnets. This Short Review interprets Ga substitution as chemical electronic‐structure engineering rather than simple rigid‐band doping and identifies decisive ...
Ke Zou
wiley +1 more source

