Rh(II) catalyzed efficient sigmatropic rearrangement reaction of pyridotriazoles and sulfides
Green Synthesis and Catalysis, 2023 The [2,3]- and [1,2]-sigmatropic rearrangement reactions between pyridotriazoles and sulfides catalyzed by rhodium(II) were investigated. The utilization of pyridotriazoles as the carbene precursors in this kind of reaction efficiently constructed the C ...
Yuting Chen +6 more
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Organocatalytic C─O Bond Cleavage and Asymmetric Transformations via [1,3]‐Sigmatropic Rearrangement [PDF]
Advanced ScienceHere, an organocatalytic asymmetric [1,3]‐sigmatropic rearrangement process for aryl ether insertion through C─O bond cleavage and downstream transformation is reported, enabling the practical and atom‐economic synthesis of diverse valuable chiral ...
Lei Peng +7 more
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Design and Experimental Validation of a Photocatalyst Recommender Based on a Large Language Model. [PDF]
Angew Chem Int Ed EnglChoosing a photocatalyst for a given reaction can be challenging due to complex mechanisms and multiple parameters that govern the outcome of a photocatalyzed reaction. Herein, we disclose a machine learning (ML) model that can suggest catalysts for a given reaction using an online portal.
Millward F +13 more
europepmc +3 more sources
[2,3]-Sigmatropic rearrangement with [1.1.1]propellane [PDF]
Nature CommunicationsThe most established reactivity of [1.1.1]propellane involves addition reactions at the bridge C-C bond, resulting in the formation of bicyclo[1.1.1]pentane derivatives.
Suparnak Midya +2 more
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Regioselective [5,5]‐Sigmatropic Rearrangement Reactions of Aryl Hydrazides. [PDF]
ChemInform, 2006 AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Hong-Min, Kang +4 more
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Sequential Diels–Alder/[3,3]-sigmatropic rearrangement reactions of β-nitrostyrene with 3-methyl-1,3-pentadiene [PDF]
Beilstein Journal of Organic Chemistry, 2013 The tin(IV)-catalyzed reaction of β-nitrostyrene with (E)-3-methyl-1,3-pentadiene in toluene afforded two major nitronic ester cycloadducts in 27% and 29% yield that arise from the reaction at the less substituted diene double bond.
Peter A. Wade +3 more
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Domino reaction of 3-nitro-2-(trifluoromethyl)-2H-chromenes with 2-(1-phenylalkylidene)malononitriles: synthesis of functionalized 6-(trifluoromethyl)-6H-dibenzo[b,d]pyrans and a rare case of [1,5] sigmatropic shift of the nitro group [PDF]
, 2013 A variety of functionalized 6-(trifluoromethyl)-6H-dibenzo[b,d]pyrans were easily synthesized in good yields under mild conditions by a domino reaction of 3-nitro-2-(trifluoromethyl)-2H-chromenes with 2-(1-phenylethylidene)- and 2-(1-phenylpropylidene ...
Vladislav Yu. Korotaev +2 more
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Theoretical investigation of Banert cascade reaction [PDF]
Royal Society Open Science, 2018 Computational inside of Banert cascade reaction for triazole formation is studied with B3LYP/6-31G(d,p) level of theory. The reaction proceeds mainly by SN2 initial chloride displacement rather than SN2′-type attack. Furthermore, according to the rate of
S. Bhattacharyya, K. Hatua
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Copper-Catalyzed Synthesis of Axially Chiral Biaryls with Diaryliodonium Salts as Arylation Reagents
Molecules, 2021 NOBIN and BINAM derivatives harboring biaryl frameworks are recognized as a class of important atropisomers with versatile applications. Here, we present an efficient synthetic route to access such compounds through copper-catalyzed domino arylation of N-
Ji-Wei Zhang +3 more
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Claisen Rearrangement Toward Cyclic Compound on Different Organic Synthesis Methods: Short Review
Chempublish Journal, 2023 The synthesis of functional and complex organic compounds is majorly performed by the Claisen rearrangement method. Claisen rearrangement is one of [3,3] sigmatropic rearrangements, a complex method in the synthesis of organic compounds, where it is ...
Rizki Rachmad Saputra +7 more
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