Results 61 to 70 of about 6,329 (228)
Recent Advances in Stereospecific Transformations of Organoboron Reagents
Transformative Chemistry, Volume 1, Issue 1, December 2025.Enantioenriched boronic esters when activated with organolithiums, can be transformed into boronate complexes that act as chiral organometallic‐type nucleophiles and can engage a wide variety of electrophiles in stereospecific cross‐coupling reactions.
Shubham Ojha +3 more
wiley +1 more source
Journal of the Brazilian Chemical Society, 1999 The Rh2(OAc)4 catalyzed intramolecular O-H insertion reaction of delta-hydroxy-alpha-diazoesters affords 3(2H)-furanone-2-carboxylates in good yield but with moderate selectivity (d.e. ca 60%).
Padwa Albert, Sá Marcus Mandolesi
doaj
Automatic mapping of atoms across both simple and complex chemical reactions [PDF]
, 2019 Mapping atoms across chemical reactions is important for substructure searches, automatic extraction of reaction rules, identification of metabolic pathways, and more.
A Bøgevig +36 more
core +3 more sources
The Chemical Record, Volume 25, Issue 12, December 2025.Systematic overview of pyrazole functionalization reactions from C‐5 to N−H. It covers different strategies, from traditional cross‐coupling of prefunctionalized pyrazoles to more efficient direct functionalizations. This review briefly and systematically overviews C–H and N–H functionalization reactions of pyrazoles, aimed at creating new CC and C ...
Karolina Dzedulionytė Müldür +3 more
wiley +1 more source
Chemistry, Applications, and Synthesis Methods of Indole Derivatives: A Comprehensive Review
The Chemical Record, Volume 25, Issue 12, December 2025.Indole and its derivatives represent a vital class of heterocycles with broad applications in pharmaceuticals, agrochemicals, and materials science. This review explores their applications, biosynthesis, key derivatives such as tryptophan, and presents an overview of both classical and modern synthetic methodologies, with a focus on sustainable ...
Raphael Silva Moratório de Moraes +10 more
wiley +1 more source
Recent Advances in Ene Reactions with Carbon Enophiles
Advanced Synthesis &Catalysis, Volume 367, Issue 22, November 28, 2025.Recent advances in the classical intra‐ and intermolecular ene nexus with carbon enophiles (alkenes, alkynes, arynes, and allenes) show a considerable increase in structural complexity and an enormous potential for functional applications in polymer science.
Thomas J. J. Müller
wiley +1 more source
1,3‐Diazetidin‐2‐Ones: Synthetic Approaches and Therapeutic Promise within the Aza‐β‐Lactam Family
European Journal of Organic Chemistry, Volume 28, Issue 43, November 24, 2025.This review explores the synthesis, reactivity, and therapeutic potential of 1,3‐diazetidin‐2‐ones—an underexplored class of aza‐β‐lactams. Emphasis is placed on synthetic challenges, emerging methodologies, and their promise as β‐lactamase‐resistant scaffolds in medicinal chemistry. 1,3‐diazetidin‐2‐ones, overlooked members of the aza‐β‐lactam family,
Jozef Kristek, Jiří Pospíšil
wiley +1 more source
Development of an Efficient Stereoretentive Para‐Claisen‐Cope Rearrangement
ChemistryEurope, Volume 3, Issue 6, November 11, 2025.The stereoretentive para‐Claisen‐Cope rearrangement enabled by Europium catalysis is presented, achieving precise phenol functionalization with exceptional chirality transfer under air‐ and moisture‐tolerant conditions. A novel carbonate unlocks superior enantioselectivity in the Tsuji‐Trost allylic alkylation, paving the way for highly enantioenriched
Johanna Breinsperger +3 more
wiley +1 more source
Anionic sigmatropic-electrocyclic-Chugaev cascades: accessing 12-aryl-5-(methylthiocarbonylthio)tetracenes and a related anthra[2,3-b]thiophene [PDF]
, 2015 1,4-Diols resulting from the double addition of ArCCLi (Ar = Ph, substituted phenyl, 2-thienyl) to ortho-C6H4(CHO)2 undergo cascades to tetracenes on simple admixture of LiHDMS, CS2 and MeI.
Burroughs, Laurence +5 more
core +3 more sources